Product: BTT-Tapt COF
Synonyms:DA-COF-2
CAS:2768475-11-0
Basic Information
Unit MF. |
C21H18N6.C15H6O3S3 |
Unit MW. |
684.80916 |
Linkers |
1) benzo[1,2-b:3,4-b':5,6-b'']trithiophene-2,5,8-tricarbaldehyde(CAS: 2243590-42-1)
2) 1,3,5-tris-(4-aminophenyl)triazine (CAS:14544-47-9)
|
Aperture |
1.6 nm |
Pore volume |
0.81 cm³/g |
Surface Area |
BET比表面积约为1269 m²/g |
Analog Structure |
 |
Product Property
Appearance |
Brown solid |
 |
Particle Size |
/ |
Stability
1) The thermogravimetric analysis (TGA) of DA-COF-2 under nitrogen atmosphere showed thermal stability up to 300 ° C.
2) After soaking in water, hexane, 12 M HCl, and 12 M NaOH solvents for 24 hours, DA-COF-2 maintained its original PXRD mode and exhibited good chemical stability.
Preservation
1) Dry and sealed under normal temperature or low temperature conditions
2) It is recommended to activate for 12 hours at 60 degree in vacuum before gas adsorption test
Other Features
Fluorescence:NA
Applications
1) Photocatalysis and photovoltaic applications, especially as functional platforms for perovskite solar cells, have improved photovoltaic conversion efficiency and stability.
2) Due to its high crystallinity, good porosity, and excellent stability, it may have potential applications in materials adsorption/separation, sensors, proton conduction, heterogeneous catalysis, and other fields.
Characterizations
References
1) Zhongping Li, Zhenwei Zhang, Riming Nie,* Chunzhi Li, Qikun Sun, Wei Shi,Weicun Chu, Yuyang Long, He Li,* and Xiaoming Liu*;Adv. Funct. Mater. 2022, 32, 2112553;DOI: 10.1002/adfm.202112553;Construction of Stable Donor–Acceptor Type Covalent Organic Frameworks as Functional Platform for Effective Perovskite Solar Cell Enhancement;