Home > Product Category > COFs-HOF-POF > COFs by Functions > COFs for Post-Synthesis > Metal-Chelatable COFs
CAS:2641745-83-5
M.F.:C34H22O4.C10H10N4
M.W.:680.75
Pricing
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Product: TFBP - Bpy COF
Synonyms: None
CAS：None
Basic Information
| Unit MF. | Not mentioned in the literature | Unit MW. | Unable to calculate | ||
| Coordination Metal | Rh | Linkers |
1,2,4,5 - Tetrakis(4 - formylphenyl)benzene (TFBP), 6 - (5 - aminopyridin - 2 - yl)pyridin - 3 - amine |
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| Pore Size | Not mentioned in the literature | Pore volume | Not mentioned in the literature | ||
| Surface Area | Not mentioned in the literature | ||||
| Analog Structure | No relevant information | ||||
Product Property
| Appearance | Uniform spherical shape with a smooth surface | |||
| Particle Size | Average diameter is 1.8μm | |||
Stability
1) Stability in solution is not mentioned in the literature.
2) Thermal stability: Thermal decomposition temperature is not mentioned in the literature, and detailed information on thermal stability is not clear.
2) Thermal stability: Thermal decomposition temperature is not mentioned in the literature, and detailed information on thermal stability is not clear.
Preservation
1) Store in a dry and sealed condition at room temperature or low temperature.
2) It is recommended to activate in a vacuum oven at room temperature for 3 hours before use. (Using the conventional method in the template, as no special preservation and activation methods are mentioned in the literature.)
Other Features
Fluorescence: No relevant information.
Other: Nitrogen - containing groups can stabilize metal atoms and form strong coordination bonds.
Other: Nitrogen - containing groups can stabilize metal atoms and form strong coordination bonds.
Applications
1) Used for one - pot tandem reductive amination of aldehydes to prepare secondary imines.
2) Can catalyze the reaction of a variety of substituted aromatic aldehyde compounds to form corresponding secondary imines.
2) Can catalyze the reaction of a variety of substituted aromatic aldehyde compounds to form corresponding secondary imines.
Characterizations
References
1) Nan Wang, Jianguo Liu, Long Tang, Xiuzhi Wei, Chenguang Wang, Xinjun Li, Longlong Ma; ACS Appl. Mater. Interfaces 2021, 13, 24966−24975, DOI: 10.1021/acsami.1c05732; Facile Synthesis of Rh Anchored Uniform Spherical COF for One - Pot Tandem Reductive Amination of Aldehydes to Secondary Imines