Product Name:1,1,2,2-tetrakis[4-phosphonophenyl]ethyleneSynonymous:H8TPPE;tetraphenylethylene tetraphosphonic acid CAS:2485827-21-0
Basic Info
M.F. |
C26H24O12P4 |
M.W. |
652.35676 |
Appearance |
|
Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:[Ni2(H4TPPE)(H2O)6]·4H2O / CAU-46 , [Co2(H4TPPE)(H2O)4]·3H2O / CAU-47 [r1]; M-CAU-53 (M = Al3+, Ga3+, Fe3+) [r3];
Characterization
Reference
1) Woehlbrandt, Stephan; Meier, Christoph; Reinsch, Helge; Svensson Grape, Erik; Inge, A. Ken; Stock, Norbert; Inorg. Chem. 2020, 59(18), 13343-13352, DOI: 10.1021/acs.inorgchem.0c01703 ; A Tetratopic Phosphonic Acid for the Synthesis of Permanently Porous MOFs: Reactor Size-Dependent Product Formation and Crystal Structure Elucidation via Three-Dimensional Electron Diffraction
2) Chakraborty, Debabrata; Ghorai, Arijit; Chowdhury, Avik; Banerjee, Susanta; Bhaumik, Asim; Chem.-Asian J. 2021, 16(12), 1562-1569, DOI: 10.1002/asia.202100270 ; A Tetradentate Phosphonate Ligand-based Ni-MOF as a Support for Designing High-performance Proton-conducting Materials
3) Steinke, Felix; Javed, Ali; Woehlbrandt, Stephan; Tiemann, Michael; Stock, Norbert; Dalton Trans. 2021, 50(38), 13572-13579, DOI: 10.1039/d1dt02610k ; New isoreticular phosphonate MOFs based on a tetratopic linker
4) Chakraborty, Debabrata; Bej, Sourav; Sahoo, Sumanta; Chongdar, Sayantan; Ghosh, Anirban; Banerjee, Priyabrata; Bhaumik, Asim; ACS Sustainable Chem. & Eng. 2021, 9(42), 14224-14237, DOI: 10.1021/acssuschemeng.1c04877 ; Novel Nanoporous Ti-Phosphonate Metal-Organic Framework for Selective Sensing of 2,4,6-Trinitrophenol and a Promising Electrode in an Energy Storage Device