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CAS:2485827-21-0 M.F.:C26H24O12P4 M.W.:652.35676
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Product Name:1,​1,​2,​2-​tetrakis[4-​phosphonophenyl]​ethylene
Synonymous:H8TPPE;tetraphenylethylene tetraphosphonic acid
CAS:2485827-21-0
Basic Info
M.F. C26H24O12P4 M.W. 652.35676
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:[Ni2(H4TPPE)​(H2O)​6]​·4H2O / CAU-​46 , [Co2(H4TPPE)​(H2O)​4]​·3H2O / CAU-​47 [r1]; M-​CAU-​53 (M = Al3+, Ga3+, Fe3+)​ [r3];
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Woehlbrandt, Stephan; Meier, Christoph; Reinsch, Helge; Svensson Grape, Erik; Inge, A. Ken; Stock, Norbert; Inorg. Chem. 2020, 59(18), 13343-13352, DOI: 10.1021/acs.inorgchem.0c01703 ; A Tetratopic Phosphonic Acid for the Synthesis of Permanently Porous MOFs: Reactor Size-​Dependent Product Formation and Crystal Structure Elucidation via Three-​Dimensional Electron Diffraction
2) Chakraborty, Debabrata; Ghorai, Arijit; Chowdhury, Avik; Banerjee, Susanta; Bhaumik, Asim; Chem.-Asian J. 2021, 16(12), 1562-1569, DOI: 10.1002/asia.202100270 ; A Tetradentate Phosphonate Ligand-​based Ni-​MOF as a Support for Designing High-​performance Proton-​conducting Materials
3) Steinke, Felix; Javed, Ali; Woehlbrandt, Stephan; Tiemann, Michael; Stock, Norbert; Dalton Trans. 2021, 50(38), 13572-13579, DOI: 10.1039/d1dt02610k ; New isoreticular phosphonate MOFs based on a tetratopic linker
4) Chakraborty, Debabrata; Bej, Sourav; Sahoo, Sumanta; Chongdar, Sayantan; Ghosh, Anirban; Banerjee, Priyabrata; Bhaumik, Asim; ACS Sustainable Chem. & Eng. 2021, 9(42), 14224-14237, DOI: 10.1021/acssuschemeng.1c04877 ; Novel Nanoporous Ti-​Phosphonate Metal-​Organic Framework for Selective Sensing of 2,​4,​6-​Trinitrophenol and a Promising Electrode in an Energy Storage Device

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