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Benzoic acid,4,4'-sulfonylbis-
Benzoic acid,4,4'-sulfonylbis-
CAS:2449-35-6 M.F.:C14H10O6S M.W.:306.290603160858
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Product Name:4,4'-sulfonylbis-Benzoic acid
Synonymous:H2SDB; H2DCPS ; 4,​4'-​Sulfonylbis[benzoic acid]​; 4,​4'-​Dicarboxydiphenyl sulfone; 4,​4'-​Sulfonyldibenzoic acid; Bis(4-​carboxyphenyl) sulfone; Diphenylsulfone-​4,​4'-​dicarboxylic acid
CAS:2449-35-6
Basic Info
M.F. C14H10O6S M.W. 306.2906
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis: MOF-114 [r2]; IITKGP-​6 [r4] ; CYCU-​1 / Ca(SBA) [r5]; [Al(OH)​(SDBA)​] / CAU-11 [r6];
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
 1) Boyarskii, V. P.; Zhesko, T. E.; Lanina, S. A.; Russ. J. Appl. Chem. 2005, 78, 1844-1848, DOI: 10.1007/s11167-005-0619-y ; Synthesis of Aromatic Carboxylic Acids by Carbonylation of Aryl Halides in the Presence of Epoxide-​Modified Cobalt Carbonyls as Catalysts
2) Furukawa, Hiroyasu; Kim, Jaheon; Ockwig, Nathan W.; O'Keeffe, Michael; Yaghi, Omar M.; J. Am. Chem. Soc. 2008, 130(35), 11650-11661, DOI: 10.1021/ja803783c ; Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal-​Organic Frameworks and Polyhedra
3) Chen, Shuguang; Shi, Zhenzhen; Qin, Ling; Jia, Hailang; Zheng, Hegen; Cryst. Growth & Des. 2017, 17(1), 67-72, DOI: 10.1021/acs.cgd.6b01197 ; Two New Luminescent Cd(II)​-​Metal-​Organic Frameworks as Bifunctional Chemosensors for Detection of Cations Fe3+, Anions CrO42-​, and Cr2O72- in Aqueous Solution
4) Pal, Arun; Chand, Santanu; Das, Madhab C.; Inorg. Chem. 2017, 56(22), 13991-13997, DOI: 10.1021/acs.inorgchem.7b02136 ; A Water-​Stable Twofold Interpenetrating Microporous MOF for Selective CO2 Adsorption and Separation
5) Yeh, Chun-Ting; Lin, Wei-Cheng; Lo, Sheng-Han; Kao, Ching-Che; Lin, Chia-Her; Yang, Chun-Chuen; CrystEngComm 2012, 14(4), 1219-1222, DOI: 10.1039/c2ce05875h ; Microwave synthesis and gas sorption of calcium and strontium metal-​organic frameworks with high thermal stability
6) Reimer, Nele; Reinsch, Helge; Inge, A. Ken; Stock, Norbert; Inorg. Chem. 2015, 54(2), 492-501, DOI: 10.1021/ic502242j ; New Al-​MOFs Based on Sulfonyldibenzoate Ions: A Rare Example of Intralayer Porosity
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Benzoic acid,4,4'-sulfonylbis-
Benzoic acid,4,4'-sulfonylbis-

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