Product: Bpy-CTF
Synonyms: CTF-HUST-S4;;CTF-BPy COF;1,4-Benzenedicarboximidamide, hydrochloride (1:2), polymer with [2,2′-bipyridine]-5,5′-dicarboxaldehyde
CAS:2415171-38-7
Basic Information
Unit MF. |
C12H8N2O2.C8H10N4.2ClH |
Unit MW. |
447.32 |
Coordination Metal |
|
Linkers |
1) 5,5'-Diformyl-2,2'-bipyridine(CAS:135822-72-9); 2) benzene-1,4-dicarboximidamide dihydrochloride(CAS:14401-56-0)
|
Pore Size |
~1.27 nm |
Pore Volume |
0.68 cm³/g |
Surface Area |
675 m²/g |
Analog Structure |
/ |
Product Property
Appearance |
Grey purple powders |
|
Particle Size |
0.5 - 2 µm |
Stability
1) Stable in water with good hydrophilicity.
2) Thermal decomposition temperature > 600°C.
Preservation
1) Keep in dry and cool condition.
2) Activation by heating in a vacuum oven at room temperature for 3 hours.
Other Features
No significant fluorescence.
Applications
1) Photocatalytic water oxidation under visible light (≥420 nm).
2) Suitable for visible-light-driven photocatalytic reactions.
Characterizations
References
1) Chen, Hongmei; Gardner, Adrian M.; Lin, Guoan; Zhao, Wei; Bahri, Mounib; Browning, Nigel D.; Sprick, Reiner Sebastian; Li, Xiaobo; Xu, Xiaoxiang; Cooper, Andrew I.; Catalysis Science & Technology 2022, 12, 5442–5452, DOI: 10.1039/d2cy00773h, Covalent triazine-based frameworks with cobalt loading for visible light-driven photocatalytic water oxidation