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TAPT-PDAN COF
TAPT-PDAN COF
CAS:2353523-07-4
M.F.:C24H15N3O3.C10H8N2
M.W.:549.57812
Pricing
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Product: TAPT-PDAN-COF
Synonyms:
CAS：
Basic Information
| Unit MF. | Unit MW. | ||||
| Linkers | TAPT PDAN | ||||
| Pore Size | ~2 nm | Pore volume | 0.19 cm³/g | ||
| Surface Area | ~200 m²/g | ||||
| Analog Structure | Not Mentioned | ||||
Product Property
| Appearance | Yellow crystalline solid with bright solid-state fluorescence | |||
| Particle Size | irregular cluster particles | |||
Stability
1) Highly stable in solutions
2) Thermal stability: High thermal stability, stable up to 600°C
2) Thermal stability: High thermal stability, stable up to 600°C
Preservation
1) Store in a dry and sealed condition at room temperature or low temperature
2) It is recommended to activate in a vacuum oven at room temperature for 3 hours before use.
Other Features
Fluorescence: It has solid-state fluorescence. Compared with the model compound A, its UV-Vis and fluorescence spectra show obvious red shifts of 55 nm and 37 nm respectively (adsorption and emission wavelengths are not mentioned). It is an excellent semiconductor material with a LUMO of -3.23 eV and a band gap of 2.36 eV. It has a highly conjugated structure and can strongly bind to NAD⁺ through π-π stacking interactions, promoting photoinduced charge transfer.
Applications
1) Used in photocatalytic coenzyme regeneration, which can significantly improve the coenzyme regeneration efficiency, such as for NADH regeneration.
2) Applied in coenzyme-assisted synthesis of L-glutamate, achieving a record-high yield of 97% within 12 minutes.
2) Applied in coenzyme-assisted synthesis of L-glutamate, achieving a record-high yield of 97% within 12 minutes.
Characterizations
References
1) Yingjie Zhao, Hui Liu, Chenyu Wu, Zhaohui Zhang, Qingyan Pan, Fan Hu, Ruiming Wang, Piwu Li, Xiaowen Huang, Zhibo Li; Angew. Chem. Int. Ed. 2019, 10.1002/anie.201901194, Angew. Chem. 2019, 10.1002/ange.201901194; Fully sp2-Carbon Conjugated Two-Dimensional Covalent Organic Frameworks as Artificial Photosystem I with Unprecedented Efficiency
2) Shunqi Xu, Zhongquan Liao, Arezoo Dianat, Sang-Wook Park, Matthew A. Addicoat, Yubin Fu, Dominik L. Pastoetter, Filippo Giovanni Fabozzi, Yannan Liu; Angew. Chem. Int. Ed. 2022, 10.1002/anie.202202492; Combination of Knoevenagel Polycondensation and Water-Assisted Dynamic Michael-Addition-Elimination for the Synthesis of Vinylene-Linked 2D Covalent Organic Frameworks