Product: IISERP-COF9
Synonyms: TPP-HTD COF
CAS: 2306024-28-0
Basic Information
Unit MF. |
C23H20N4.C9H6O4 |
Unit MW. |
530.57 |
Coordination Metal |
None |
Linkers |
2-Hydroxybenzene-1,3,5-tricarbaldehyde 4,4',4''-(Pyridine-2,4,6-triyl)trianiline
|
Pore Size |
~13.5 Å |
Pore Volume |
0.2 cm³/g |
Surface Area |
1172 m²/g |
Analog Structure |
/ |
Product Property
Appearance |
Brown powders, spherical structure composed of aggregated COF flakes |
|
Particle Size |
2-3 nm (thickness of COF flakes) |
Stability
1) Stable in water, acids (6N HCl), and bases (6N NaOH)
2) Thermal decomposition temperature > 350°C
Preservation
1) Store in a dry and cool condition
2) No special activation required before use
Other Features
Fluorescence: NA
Applications
1) Heterogeneous catalyst for Glaser-Hay coupling reactions to synthesize unsymmetrical diynes
2) Stabilization of Cu/Cu₂O nanoparticles for catalysis
3) High thermal stability for high-temperature catalytic applications
Characterizations
References
1) Chakraborty, Debanjan; Nandi, Shyamapada; Mullangi, Dinesh; Haldar, Sattwick; Vinod, Chathakudath P.; Vaidhyanathan, Ramanathan; ACS Applied Materials & Interfaces 2019, 11, 15670−15679. DOI: 10.1021/acsami.9b02860; Cu/Cu₂O Nanoparticles Supported on a Phenol−Pyridyl COF as a Heterogeneous Catalyst for the Synthesis of Unsymmetrical Diynes via Glaser−Hay Coupling