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COF-F
COF-F
CAS:2291327-81-4
M.F.:(C21H18N6.C8H2F4O2)X
M.W.:560.50
Pricing
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Product: COF-F
Synonyms: SCF-FCOF-1
CAS：2291327-81-4
Basic Information
| Unit MF. | (C21H18N6.C8H2F4O2)x | Unit MW. | 560.50 | ||
| Linkers |
1) 1,3,5-tris-(4-aminophenyl)triazine（CAS: 14544-47-9） 2) 2,3,5,6-Tetrafluoroterephthalaldehyde (CAS:3217-47-8 ) |
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| Aperture | 33 Å | Pore volume | cm3/g | ||
| Surface Area | BET比表面积1000 m²/g+ | ||||
| Analog Structure | |||||
Product Property
| Appearance | powder | |||
| Particle Size | / | |||
Stability
1) SCF-FCOF-1 is insoluble in water and common organic solvents, demonstrating good chemical stability.
Preservation
1) Dry and sealed under normal temperature or low temperature conditions
2) It is recommended to activate for 12 hours at 120 degree in vacuum before gas adsorption test
2) It is recommended to activate for 12 hours at 120 degree in vacuum before gas adsorption test
Other Features
Fluorescence:NA
Applications
1) It can be used for gas storage and separation;
2) The imine group has Lewis alkalinity and can be used as a catalyst or catalyst carrier for various chemical reactions, including redox reactions, C-C coupling reactions, and photocatalytic reactions;
3) It can serve as a carrier for drug molecules, used for targeted drug delivery and controlled release;
4) SCF-FCOF-1 exhibits excellent selective adsorption performance and good recyclability due to its high specific surface area, crystallinity, hydrophobicity, and electrostatic attraction between fluorine atoms and guest molecules.
Characterizations
References
1) Liao, Qiaobo; Ke, Can; Huang, Xin; Zhang, Guiyang; Zhang, Qi; Zhang, Zewei; Zhang, Yiying; Liu, Yunzhong; Ning, Fangyi; Xi, Kai;Journal of Materials Chemistry A: Materials for Energy and Sustainability (2019), 7(32), 18959-18970 ; DOI: 10.1039/c9ta06214a ;Catalyst-free and efficient fabrication of highly crystalline fluorinated covalent organic frameworks for selective guest adsorption