TFPA-TAPT COF | TPA-TCIF COF | CAS:2268016-66-4

Product: TFPA-TAPT COF
Synonyms: TPA-TCIF COF
CAS：2268016-66-4

Basic Information

Unit MF.	(C21H18N6.C21H15NO3)x	Unit MW.	683.76
Linkers	1) 4,4',4''-Nitrilotribenzaldehyde （CAS: 119001-43-3） 2) (1,3,5-tris-(4-aminophenyl)triazine (CAS:14544-47-9)
Aperture	1.5 nm	Pore volume	1.23 cm³/g
Surface Area	BET比表面积为2900 m²/g
Analog Structure

Product Property

Appearance	Cauliflower like morphology
Particle Size	/

Stability

1) It exhibits high stability in water and various organic solvents;

Preservation

1) Dry and sealed under normal temperature or low temperature conditions
2) Activation method: TPA-TCIF is vacuum dried at 200 ° C in an inert atmosphere for 10 hours

Other Features

Fluorescence:NA

Applications

1) It can be used for gas storage and separation;

2) The imine group has Lewis alkalinity and can be used as a catalyst or catalyst carrier;

3) It can serve as a carrier for drug molecules, used for targeted drug delivery and controlled release;

4) It can be used for water treatment and pollutant adsorption, such as removing heavy metal ions and organic pollutants from water;

Characterizations

XRD

SEM

BET

FTIR

References

1) Puthiaraj, Pillaiyar; Kim, Hyun Sub; Yu, Kwangsun; Ahn, Wha-Seung; Microporous and Mesoporous Materials 2020 , 297, 110011pp; DOI: 10.1016/j.micromeso.2020.110011 ; Triphenylamine-based covalent imine framework for CO2 capture and catalytic conversion into cyclic carbonates
2) Puthiaraj, Pillaiyar; Yu, Kwangsun; Shim, Sang Eun; Ahn, Wha-Seung;Molecular Catalysis 2019 , 473, 110395 ; DOI: 10.1016/j.mcat.2019.110395 ;Pd(II)-immobilized on a nanoporous triazine-based covalent imine framework for facile cyanation of haloarenes with K4Fe(CN)6