1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy-, polymer with N1,N1-bis(4-aminophenyl)-1,4-benzenediamine
1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy-, polymer with N1,N1-bis(4-aminophenyl)-1,4-benzenediamine
CAS:2253172-56-2
M.F.:C18H18N4.C9H6O6
M.W.:500.50266
Pricing
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Product: TAPA-TFP COF
Synonyms: TFP-TAPA
CAS：
Basic Information
| Unit MF. | / | Unit MW. | / | ||
| Coordination Metal | Linkers | / | |||
| Pore Size | 1.3nm | Pore volume | ~0.4 cm³/g, | ||
| Surface Area | > 400m²/g | ||||
| Analog Structure | / | ||||
Product Property
| Appearance | Brown Solid | |||
| Particle Size | irregular cluster particles or spheric cluster particles | |||
Stability
1) Stability in solution is not mentioned in the literature.
2) Thermal stability: slight weight loss between 100 - 500°C, thermal decomposition temperature above 600°C, the residual mass 68% at 600℃
2) Thermal stability: slight weight loss between 100 - 500°C, thermal decomposition temperature above 600°C, the residual mass 68% at 600℃
Preservation
1) Keep in a dry and sealed condition.
2) It is recommended to activate in a vacuum oven at room temperature for 3 hours before use
Other Features
Fluorescence: Not mentioned.
Other: It has an adjustable pore structure, and the pore size can be homogenized through multi-site alkylation. It also has good γ-ray irradiation stability. After being irradiated with 10⁵ Gy γ-rays, the FTIR spectrum hardly changes.
Other: It has an adjustable pore structure, and the pore size can be homogenized through multi-site alkylation. It also has good γ-ray irradiation stability. After being irradiated with 10⁵ Gy γ-rays, the FTIR spectrum hardly changes.
Applications
1) Used for efficient sieving of Xe/Kr mixed gases, with a high adsorption capacity and selectivity for Xe.
2) As a drug carrier, when loaded with paclitaxel, it can inhibit the proliferation of ovarian cancer cells and reduce the migration rate of cancer cells.
2) As a drug carrier, when loaded with paclitaxel, it can inhibit the proliferation of ovarian cancer cells and reduce the migration rate of cancer cells.
Characterizations
References
1) Zhimin Jia, Zhaotong Yan, Jie Zhang, Yingdi Zou, Yue Qi, Xiaofeng Li, Yang Li, Xinghua Guo, Chuting Yang, Lijian Ma; ACS Applied Materials & Interfaces 2020, 13(1), DOI: 10.1021/acsami.0c19427; Pore Size Control via Multiple-Site Alkylation to Homogenize Sub-Nanoporous Covalent Organic Frameworks for Efficient Sieving of Xenon/Krypton
2) Atikur Hassan, Sraddhya Roy, Ananya Das, Sk Abdul Wahed, Aparajita Bairagi, Subhadip Mondal, Nabanita Chatterjee, Neeladri Das; ACS Biomaterials Science & Engineering 2024, 10(7), DOI: 10.1021/acsbiomaterials.4c00397; Covalent Organic Frameworks as Potential Drug Carriers and Chemotherapeutic Agents for Ovarian Cancers
3) Michael C. Daugherty, Edon Vitaku, Rebecca L. Li, Austin M. Evans, Anton D. Chavez, William R. Dichtel; Chem. Commun. 2019, DOI: 10.1039/C8CC08957D; Improved Synthesis of β-Ketoenamine-Linked Covalent Organic Frameworks via Monomer Exchange Reactions