CAS:2253172-55-1
M.F.:C9H6O6.C13H12N2
M.W.:406.38812
Pricing
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Product: TpDAF-COF
Synonyms: NA
CAS: NA
Basic Information
| Unit MF. | C34H26N4O4 | Unit MW. | 530.59 | ||
| Coordination Metal | None | Linkers |
1,3,5-triformylphloroglucinol (Tp) and 9H-fluorene-2,7-diamine (DAF) |
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| Pore Size | 1.26 nm | Pore Volume | NA | ||
| Surface Area | 1204 m²/g | ||||
Product Property
| Appearance | Yellow powders | |||
| Particle Size | Micron-sized spherical particles | |||
Stability
1) TpDAF-COF is stable under light irradiation and reaction conditions
2) Thermal decomposition temperature is above 400°C
2) Thermal decomposition temperature is above 400°C
Preservation
1) Keep in dry and cool conditions
2) Activate by heating in a vacuum oven at room temperature for 3 hours before use
Other Features
1) Broad absorption in the visible light region
2) Bandgap of 2.13 eV
3) n-type semiconductor characteristics
2) Bandgap of 2.13 eV
3) n-type semiconductor characteristics
Applications
1) Efficient in photocatalytic selective oxidation of amines under visible light
2) Acts as an electron transfer mediator in photocatalytic oxidation reactions
2) Acts as an electron transfer mediator in photocatalytic oxidation reactions
Characterizations
References
Kanghui Xiong, Keke Zhang, Fulin Zhang, Bing Zeng, Xianjun Lang; Journal of Colloid and Interface Science 2025, 681, 250–260, DOI: 10.1016/j.jcis.2024.11.105; Engineering fluorene-based covalent organic framework photocatalysts toward efficient and selective aerobic oxidation of amines