CTF-1 | CAS: 2155822-92-5 | CAS: 2173362-13-3 | CHEMSOON-Professional COFs Supplier

Product：CTF-1
Synonyms：CTF-HUST-1
CAS：2155822-92-5 or 2173362-13-3

Basic Information

Unit MF.	C40H24N2	Unit MW.	532.66
Linkers	Benzene-1,4-dicarboximidamide dihydrochloride CAS: 14401-56-0; 1,4-Phthalaldehyde CAS: 623-27-8
Aperture	1.2 nm	Pore volume	0.40 cm3/g
Surface Area	BET Specific surface 520m2/g
Analog Structure

Product Property

Appearance	Yellow solid
Particle Size	irregular particle clusters

Stability

1) Py-COF is stable in air and acqeous solutions (PH 1-14)

2) Thermal decomposition temperature above 400 degree

Preservation

1) Dry and sealed under normal temperature or low temperature conditions

2) Heated in vacuum at 150 for 2-3 hours

Other Features

Fluorescence: NA

Applications

1) For gas and pollutant adsorption
2) Rigid pores can be used to load other catalysts

3) Good photocatalytical capbility for hydrogen evolution

Characterizations

XRD

SEM

BET

FTIR

References

1) P. Kuhn, M. Antonietti, A. Thomas, Angew. Chem. Int. Ed. 2008, 47, 3450–3453, DOI: 10.1002/anie.200705710 ; Porous, Covalent Triazine‐Based Frameworks Prepared by Ionothermal Synthesis

2) Wang, Kewei; Yang, Li-Ming; Wang, Xi; Guo, Liping; Cheng, Guang; Zhang, Chun; Jin, Shangbin; Tan, Bien;

Cooper, Andrew; Angew. Chem., Int. Ed. 2017, 56(45), 14149-14153, DOI: 10.1002/anie.201708548 ; Covalent Triazine Frameworks via a Low-Temperature Polycondensation Approach

3) M. Liu, Q. Huang, S. Wang, Z. Li, B. Li, S. Jin, B. Tan, Angew. Chem. Int. Ed. 2018, 57, 11968–11972, DOI: 10.1002/anie.201806664 ; Crystalline Covalent Triazine Frameworks by In Situ Oxidation of Alcohols to Aldehyde Monomers

4) M. Liu, K. Jiang, X. Ding, S. Wang, C. Zhang, J. Liu, Z. Zhan, G. Cheng, B. Li, H. Chen, S. Jin, B. Tan, Adv. Mater. 2019, 31, 1807865, DOI: 10.1002/adma.201807865 ; Controlling Monomer Feeding Rate to Achieve Highly Crystalline Covalent Triazine Frameworks