Product: MTHOF-1
Synonyms: Mortise-Tenon-type HOF
CAS:NA
Basic Information
Unit MF. |
|
Unit MW. |
|
Linkers |
N,N',N'',N'''-(ethene-1,1,2,2-tetrayltetrakis(benzene-4,1-diyl))tetraacetamide |
Pore Size |
~0.6-0.9 nm |
Pore Volume |
|
Surface Area |
>500 m²/g |
Analog Structure |
/ |
Product Property
Appearance |
Colorless needle-like crystals |
|
Particle Size |
Microcrystalline, specific size not mentioned |
Stability
1) Stable in strong acid (1 mol/L HNO₃) and strong base (1 mol/L NaOH) for one week.
2) Thermal decomposition temperature above 473 K.
Preservation
1) Keep in dry and cool condition.
2) Activate by heating at 353 K under dynamic vacuum for 10 hours.
Other Features
Fluorescence: NA
Applications
1) Efficient separation of ethane/ethylene (C2H6/C2H4) to obtain polymer-grade ethylene in one step.
2) Maintains excellent separation performance even under high humidity conditions.
Characterizations
References
1) Hengbo Li, Cheng Chen, Qing Li, Xiang Jian Kong, Yuanzheng Liu, Zhenyu Ji, Shuixiang Zou, Maochun Hong, Mingyan Wu; Angew. Chem. Int. Ed. 2024, 63, e202401754, DOI: 10.1002/anie.202401754, An Ultra-stable Supramolecular Framework Based on Consecutive Side-by-side Hydrogen Bonds for One-step C2H4/C2H6 Separation