Product: HOF-NBDA
Synonyms: NA
CAS:NA
Basic Information
Unit MF. |
C42H27NO12 |
Unit MW. |
737.66328 |
Coordination Metal |
None |
Linkers |
4',4'',4'''-nitrilotris([1,1'-biphenyl]-3,5-dicarboxylic acid) (H6NBDA)
|
Pore Size |
~0.5 nm |
Pore Volume |
0.405 cm³/g |
Surface Area |
>850 m²/g |
Analog Structure |
 |
Product Property
Appearance |
Yellow block crystals |
|
Particle Size |
Irregular polygonal shape, ~10 μm |
Stability
1) Stable in common chemical solvents (e.g., ethanol, acetone, CH3CN, CHCl3).
2) Stable in boiling water and 12M HCl for 24 hours.
3) Thermal decomposition temperature > 400°C.
Preservation
1) Store in dry and cool conditions.
2) Activate by heating at 100°C under vacuum for 10 hours.
Other Features
NA
Applications
1) Efficient separation of ethane/ethylene mixtures for polymer-grade ethylene production.
2) Potential for gas adsorption applications with high selectivity for ethane.
Characterizations
References
1) Zhou, Yunzhe; Chen, Cheng; Krishna, Rajamani; Ji, Zhenyu; Yuan, Daqiang; Wu, Mingyan; Angew. Chem. Int. Ed. 2023, 62, e202305041, DOI: 10.1002/anie.202305041, Tuning Pore Polarization to Boost Ethane/Ethylene Separation Performance in Hydrogen-Bonded Organic Frameworks