SIFSIX-Cu-TPA
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Product: SIFSIX-Cu-TPA
Synonyms: [Cu3(TPA)4(SiF6)3]
CAS: NA
Basic Information
| Unit MF. | Unit MW. | ||||
| Coordination Metal | Cu | Linkers |
Tri(pyridin-4-yl)amine (TPA) |
||
| Pore Size | ~0.5 nm | Pore Volume | 0.52 cm3/g | ||
| Surface Area | 1330 m2/g | ||||
| Analog Structure | NA | ||||
Product Property
| Appearance | Dark purple block-shaped crystals | |||
| Particle Size | Irregular bulk particles | |||
Stability
1) Stable in DMF, CH3CN, 0.1 M HCl aqueous solution, and water for up to 1 month.
2) Thermal decomposition temperature > 200°C.
2) Thermal decomposition temperature > 200°C.
Preservation
1) Store in a dry and cool condition.
2) Activate by heating at room temperature under vacuum for 3 hours.
Other Features
Fluorescence: NA
Applications
1) High acetylene storage capacity (185 cm3/g at 298 K, 1 bar).
2) Excellent C2H2/CO2 separation performance (breakthrough time up to 68 min/g at 298 K, 1 bar).
3) Potential for gas adsorption and separation applications.
2) Excellent C2H2/CO2 separation performance (breakthrough time up to 68 min/g at 298 K, 1 bar).
3) Potential for gas adsorption and separation applications.
Characterizations
References
1) Li, Hao; Liu, Caiping; Chen, Cheng; Di, Zhengyi; Yuan, Daqiang; Pang, Jiandong; Wei, Wei; Wu, Mingyan; Hong, Maochun; Angew. Chem. Int. Ed. 2021, 60, 7547–7552, DOI: 10.1002/anie.202013988, An Unprecedented Pillar-Cage Fluorinated Hybrid Porous Framework with Highly Efficient Acetylene Storage and Separation