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TPAD-COF
TPAD-COF
CAS: M.F.:C62H68N4O10.C38H32N8O2 M.W.:1661.9372
Pricing //
ProductTPAD-COF
Synonyms1,4,5,8-tetrakis(phenylamino)anthracene-9,10-dione (TPAD)-based covalent organic framework
CAS:/
Basic Information
Unit MF.   Unit MW.  
Linkers

1,4,5,8-tetrakis((4-(5,5-dimethyl-1,3-dioxan-2-yl)ph-enyl)amino)anthracene-9,10-dione (TPAD-DMO) (CAS: NA);  1,4,5,8-tetrakis((4-aminophenyl)amino)anthraxcene-9,10-dione (TPAD-NH2) (CAS: NA)

Pore Size 1.7nm Pore volume 0.1cm3/g
Surface Area BET Specific surface 700-1000 m2/g 
Analog Structure  
Product Property
Appearance

 深褐色粉末

Dark Brown powder

 
Particle Size  irregular clusters
Stability
1) Stable in aqueous solution, stable in acidic and alkaline conditions. Stable in bioling water.
2) Good thermal stablility, thermal decomposition temperature above 450℃
Preservation
1) Dry and sealed under normal temperature or low temperature conditions
2) Before gas adsorption test, activate at 150℃  for 8 hours
Other Features
Fluorescence: NA
Applications
1) For gas and pollutant adsorption
2) Rigid pores to load other catalysts
3) With ultra-hydrophilicity, TPAD COF has good moisture adsorption capacity (402cc/g at 25℃); Hydorphicility also brings good photocatalysis performance in water.
Characterizations
XRD
XRD-TPAD COF
SEM
SEM-TPAD COF
BET
BET-TPAD COF
FTIR
NA
References
 
1)Dr. Xiaoli Yan, Shanzhi Lyu, Xiao-Qi Xu, Dr. Weiben Chen, Pengna Shang, Zongfan Yang, Dr. Guang Zhang, Prof. Weihua Chen, Prof. Yapei Wang, Prof. Long Chen, Angew. Int. Ed. Chem. 2022,61,  e2022019, DOI: 10.1002/anie.202201900 ; Superhydrophilic 2D Covalent Organic Frameworks as Broadband Absorbers for Efficient Solar Steam Generation
XRD TPAD-COF CS018187.pdf Download
TPAD-COF
TPAD-COF

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