UiO-66-BDC-NH2
CAS:
M.F.:C48H34N6O32Zr6
M.W.:1754.15
Pricing
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Product: NH2-UIO-66(Zr) nanoparticles
Synonyms: NA
CAS：1260119-00-3
Basic Information
| Unit MF. | C48H34N6O32Zr6 | Unit MW. | 1754.15 | ||
| Coordination Metal | Zr | Linkers | 2-aminoterephthalic acid（CAS：10312-55-7） | ||
| Pore Size | 0.8nm; 1.1nm | Pore volume | 0.5 cm3/g | ||
| Surface Area | BET Specific surface >1000 m2/g, | ||||
| Analog Structure |   |
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Product Property
| Appearance | Yellowish Powder |  |
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| Particle Size | <200nm | |||
Stability
1) NH2-UIO-66 is stable in air, stable in aqueous and acidic conditions(stable in PH 1-12); NH2-UIO-66 nanoparticles could be decomposed in 48hours in tissue fluids.
2) High thermal stability, thermal decomposition temperature above 400 ° C
2) High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to degas for 12 hours at 120 degree in vacuum before gas adsorption test
3) Ultrasonic dispersion in methanol/ethanol/DMF
Other Features
Fluorescence: λem=456nm
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) NH2-UIO-66 has rigid framework, the amino group could be post-modified without destroying the framework of the material
2) NH2-UIO-66 has rigid framework, the amino group could be post-modified without destroying the framework of the material
Characterizations
References
1) J. H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti, S. Bordiga, K. P. Lillerud, J. Am. Chem. Soc. 2008, 130, 13850-13851, DOI: 10.1021/ja8057953 ; A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
2) S. J. Garibaya, S. M. Cohen, Chem. Commun. 2010,46, 7700-7702, DOI: 10.1039/C0CC02990D ; Isoreticular synthesis and modification of frameworks with the UiO-66 topology