HMUIO-66-NH2
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Product: HMUIO-66
Synonyms: Hierarchical Mesoporous UiO-66-NH2; HMUIO-66-NH2; HMUIO-TCPP
CAS：1260119-00-3
Basic Information
| Unit MF. | C48H34N6O32Zr6 | Unit MW. | 1754.15 | ||
| Coordination Metal | Zr | Linkers | 2-aminoterephthalic acid（CAS：10312-55-7）; 1-2% H2TCPP (CAS: 14609-54-2) | ||
| Pore Size | 0.8nm; 1.1nm; modulated 6-10nm mesopores | Pore volume | >0.8 cm3/g | ||
| Surface Area | BET Specific surface 800 m2/g, | ||||
| Analog Structure |    |
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Product Property
| Appearance | Yellowish Powder | |||
| Particle Size | 100-200nm particles | |||
Stability
1) NH2-UIO-66 is stable in air, stable in aqueous and acidic conditions(stable in PH 1-12)
2）High thermal stability, thermal decomposition temperature above 400 ° C
2）High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 6 hours at 120 degree in vacuum.
Other Features
Fluorescence: λem=456nm
Applications
1) Gas and pollutant adsorption; NH2-UIO-66 has rigid framework, the amino group could be post-modified without destroying the framework of the material
2) With mesopores of 8-10nm, HMUIO-66 is prospective in loading and fixation of macromolecular drugs, peptide, enzyme and proteins.
3) Doping with prophyrin moleculars, HMUIO-66 could be appled as biochemical sensors and thermal-dynamic therapy.
Characterizations
References
1) Zhao, Liwei; Yang, Jian; Gong, Ming; Li, Ke; Gu, Jinlou; J. Am. Chem. Soc. 2021, 143(37), 15145-15151, DOI: 10.1021/jacs.1c05674 ; Specific Screening of Prostate Cancer Individuals Using an Enzyme-Assisted Substrate Sensing Platform Based on Hierarchical MOFs with Tunable Mesopore Size
2) Li, Ke; Yang, Jian; Gu, Jinlou; Chem. Mater. 2021, 33, 2198-2205, DOI: 10.1021/acs.chemmater.1c00123 ; Spatially Organized Functional Bioreactors in Nanoscale Mesoporous MOFs for Cascade Scavenging of Intracellular ROS
3) Li, Ke; Yang, Jian; Huang, Rong; Lin, Shaoliang; Gu, Jinlou; Angew. Chem., Int. Ed. 2020, 59(33), 14124-14128, DOI: 10.1002/anie.202006124 ; Ordered Large-Pore MesoMOFs Based on Synergistic Effects of TriBlock Polymer and Hofmeister Ion