TAPB-TFPA COF | CAS:2099714-35-7

Product: TAPB-TFPA COF
Synonyms:
CAS：2099714-35-7

Basic Information

Unit MF.	(C24H21N3.C21H15NO3)x	Unit MW.	680.79
Linkers	1) 4,4',4''-Nitrilotribenzaldehyde （CAS: 119001-43-3） 2) 1,3,5-Tris(4-aminophenyl)benzene (CAS:118727-34-7)
Aperture	1.72 nm	Pore volume	0.25 cm³/g
Surface Area	BET比表面积为540 m²/g
Analog Structure

Product Property

Appearance	powder
Particle Size	/

Stability

1) It is stable in N2 environment, with a maximum stable temperature of up to 400 ° C

Preservation

1) Dry and sealed under normal temperature or low temperature conditions
2) It is recommended to activate for 12 hours at 60 degree in vacuum before gas adsorption test

Other Features

Fluorescence:NA

Applications

1) It can be used for gas storage and separation;

2) The imine group has Lewis alkalinity and can be used as a catalyst or catalyst carrier;

3) It can serve as a carrier for drug molecules, used for targeted drug delivery and controlled release;

4) It can be used for water treatment and pollutant adsorption, such as removing heavy metal ions and organic pollutants from water;

Characterizations

XRD

SEM

BET

FTIR

References

1) Zhai, Lipeng; Huang, Ning; Xu, Hong; Chen, Qiuhong; Jiang, Donglin; Chemical Communications (Cambridge, United Kingdom) 2017 , 53(30), 4242-4245 ; DOI: 10.1039/c7cc01921a ; A backbone design principle for covalent organic frameworks: the impact of weakly interacting units on CO2 adsorption;

2) Yuting Ma, Shenhui Yu, Wei Li, Di Chen, Zhenqian Zheng, Linjie Mao, Xuan Yang, Wenjun Wang, and Pingwei Liu; Angew. Chem. Int. Ed., 2024, e202416980;DOI：10.1002/anie.202416980;Rapid yet Controlled Synthesis of 2D Covalent Organic Framework Nanocapsules as High-Performance Photocatalytic【文献解读】