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Benzaldehyde, 4,4′,4′′-(1,3,5-triazine-2,4,6-triyl)tris-, polymer with 4,4′,4′′-(1,3,5-triazine-2,4,6-triyl)tris[benzenamine]
Benzaldehyde, 4,4′,4′′-(1,3,5-triazine-2,4,6-triyl)tris-, polymer with 4,4′,4′′-(1,3,5-triazine-2,4,6-triyl)tris[benzenamine]
CAS:2000996-35-8 M.F.:C24H15N3O3.C21H18N6 M.W.:747.80
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Product: TPT-COF
Synonyms: TTA-TTB COF;rTTI COF
CAS:2000996-35-8

Basic Information
Unit MF. C24H15N3O3.C21H18N6 Unit MW. 747.80
Coordination Metal None Linkers

1,​3,​5-​tris(4-​formyl-​phenyl) triazine(TTB)
1,3,5-Tris(4-aminophenyl)benzene (TTA)

Pore Size ~3.1 nm Pore Volume  
Surface Area 1419 m²/g
Analog Structure /
Product Property
Appearance Brown powders  
Particle Size Irregular bulk particles, approximately 600-1000 nm
Stability
1) Stable in acidic solutions without hydrolysis
2) Thermal decomposition temperature > 400°C
Preservation
1) Store in a dry and cool condition
2) Activate by heating at room temperature in a vacuum oven for 3 hours before use.
Other Features
Fluorescence: 
Applications
1) Gas adsorption and separation (e.g., CO₂, SO₂)
2) Catalyst support (e.g., palladium catalysts)
3) Electrochemical energy storage materials
Characterizations
XRD
NA
SEM
NA
BET
NA
FTIR
NA
References
1) Grunenberg, Lars; Savasci, Gökcen; Terban, Maxwell W.; et al. Journal of the American Chemical Society 2021, 143, 3430−3438. DOI: 10.1021/jacs.0c12249. Amine-Linked Covalent Organic Frameworks as a Platform for Postsynthetic Structure Interconversion and Pore-Wall Modification.
2) Brown, Normanda; Zhang, Qingsong; Alsudairy, Ziad; et al. ACS Sustainable Chemistry & Engineering 2024, 12, 13535−13543. DOI: 10.1021/acssuschemeng.4c04003. Mechanochemical in Situ Encapsulation of Palladium in Covalent Organic Frameworks.
Benzaldehyde, 4,4′,4′′-(1,3,5-triazine-2,4,6-triyl)tris-, polymer with 4,4′,4′′-(1,3,5-triazine-2,4,6-triyl)tris[benzenamine]
Benzaldehyde, 4,4′,4′′-(1,3,5-triazine-2,4,6-triyl)tris-, polymer with 4,4′,4′′-(1,3,5-triazine-2,4,6-triyl)tris[benzenamine]

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