Benzaldehyde, 4,4′,4′′-(1,3,5-triazine-2,4,6-triyl)tris-, polymer with 4,4′,4′′-(1,3,5-triazine-2,4,6-triyl)tris[benzenamine]
Benzaldehyde, 4,4′,4′′-(1,3,5-triazine-2,4,6-triyl)tris-, polymer with 4,4′,4′′-(1,3,5-triazine-2,4,6-triyl)tris[benzenamine]
CAS:2000996-35-8
M.F.:C24H15N3O3.C21H18N6
M.W.:747.80
Product: TPT-COF
Synonyms: TTA-TTB COF;rTTI COF
CAS:2000996-35-8
Basic Information
Unit MF. |
C24H15N3O3.C21H18N6 |
Unit MW. |
747.80 |
Coordination Metal |
None |
Linkers |
1,3,5-tris(4-formyl-phenyl) triazine(TTB) 1,3,5-Tris(4-aminophenyl)benzene (TTA)
|
Pore Size |
~3.1 nm |
Pore Volume |
|
Surface Area |
1419 m²/g |
Analog Structure |
/ |
Product Property
Appearance |
Brown powders |
|
Particle Size |
Irregular bulk particles, approximately 600-1000 nm |
Stability
1) Stable in acidic solutions without hydrolysis
2) Thermal decomposition temperature > 400°C
Preservation
1) Store in a dry and cool condition
2) Activate by heating at room temperature in a vacuum oven for 3 hours before use.
Other Features
Fluorescence:
Applications
1) Gas adsorption and separation (e.g., CO₂, SO₂)
2) Catalyst support (e.g., palladium catalysts)
3) Electrochemical energy storage materials
Characterizations
References
1) Grunenberg, Lars; Savasci, Gökcen; Terban, Maxwell W.; et al. Journal of the American Chemical Society 2021, 143, 3430−3438. DOI: 10.1021/jacs.0c12249. Amine-Linked Covalent Organic Frameworks as a Platform for Postsynthetic Structure Interconversion and Pore-Wall Modification.
2) Brown, Normanda; Zhang, Qingsong; Alsudairy, Ziad; et al. ACS Sustainable Chemistry & Engineering 2024, 12, 13535−13543. DOI: 10.1021/acssuschemeng.4c04003. Mechanochemical in Situ Encapsulation of Palladium in Covalent Organic Frameworks.