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[1,1′-Biphenyl]-4,4′-dicarboxaldehyde, polymer with 4,4′,4′′,4′′′-(1,3,6,8-pyrenetetrayl)tetrakis[benzenamine]
[1,1′-Biphenyl]-4,4′-dicarboxaldehyde, polymer with 4,4′,4′′,4′′′-(1,3,6,8-pyrenetetrayl)tetrakis[benzenamine]
CAS:1962180-64-8 M.F.:C40H30N4.C14H10O2 M.W.:776.92
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Product: Py-2P COF
Synonyms: BPD-COF;[1,1′-Biphenyl]-4,4′-dicarboxaldehyde, polymer with 4,4′,4′′,4′′′-(1,3,6,8-pyrenetetrayl)tetrakis[benzenamine]
CAS:1962180-64-8

Basic Information
Unit MF. C40H30N4.C14H10O2 Unit MW. 776.92
Coordination  Metal None Linkers

1) [1,1′-Biphenyl]-4,4′-dicarboxaldehyde(BPD)(CAS:66-98-8)
2) 4,4′,4′′,4′′′-(1,3,6,8-pyrenetetrayl)tetrakis[benzenamine] (TPy)(CAS:1610471-69-6)

Pore Size Approximately 3.7 nm Pore volume Not mentioned in the literature
Surface Area Not mentioned in the literature
Analog Structure  
Product Property
Appearance Aggregates of spherical nanoparticles, color not mentioned  
Particle Size Not mentioned in the literature
Stability
1) The stability of structure and catalytic performance in solutions with different pH values, in the presence of various ions and humic acid is not mentioned;
2) Thermal stability and thermal decomposition temperature: Not mentioned in the literature
Preservation
1) Keep in a dry and cool place, sealed.
2) It is recommended to activate in a vacuum oven at room temperature for 3 hours before use.
Other Features
1) Fluorescence: Not mentioned;
2) It has a microporous structure;
3) It can activate peroxymonosulfate (PMS) to generate ·OH and $SO_{4}^{-}$ radicals.
Applications
1) Used in the peroxymonosulfate (PMS) activation system to degrade pollutants in water.
2) It can be used as a model material for studying the reaction mechanism of PMS activation to generate radicals.
 
Characterizations
XRD
NA
SEM
NA
BET
NA
FTIR
NA
References
1) Zonglin Weng, Yuanfang Lin, Siyuan Guo, Xinfei Zhang, Qin Guo, Yu Luo, Xinwen Ou, Jinxing Ma, Yang Zhou, Jin Jiang, Bin Han; Angew. Chem. Int. Ed. 2023, 62, e202310934, DOI: 10.1002/anie.202310934; Site Engineering of Covalent Organic Frameworks for Regulating Peroxymonosulfate Activation to Generate Singlet Oxygen with 100% Selectivity;
2)Zonglin Weng, Yuanfang Lin, Siyuan Guo, Xinfei Zhang, Qin Guo, Yu Luo, Xinwen Ou, Jinxing Ma, Yang Zhou, Jin Jiang, Bin Han;Angew. Chem. Int. Ed. 2023, 62, e202310934;DOI:10.1002/anie.202310934;Site Engineering of Covalent Organic Frameworks for Regulating Peroxymonosulfate Activation to Generate Singlet Oxygen with 100% Selectivity
[1,1′-Biphenyl]-4,4′-dicarboxaldehyde, polymer with 4,4′,4′′,4′′′-(1,3,6,8-pyrenetetrayl)tetrakis[benzenamine]
[1,1′-Biphenyl]-4,4′-dicarboxaldehyde, polymer with 4,4′,4′′,4′′′-(1,3,6,8-pyrenetetrayl)tetrakis[benzenamine]

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