Material Name:Ni(pba)2 Synonyms: CAS:NA
Basic Information
Unit Formula |
C12H9NO2.Ni |
Molecular Weight |
257.89876 |
Coordination Metal |
Ni |
Linker |
4-(4-pyridyl)benzoic acid (pba) (CAS: 1192-37-7)
|
Pore Size |
~0.75 nm |
Pore Volume |
0.2 cm3/g |
Surface Area |
833.8 m2/g |
Analog Structure |
|
Product Property
Appearance |
Blue-green Crystals |
|
Particle Size |
Irregular bulk particles |
Stability
1) Stable in humid air and stable in water and ethanol
2) Thermal decomposition temperature is above 300℃
Preservation
1) Store in a dry and cool place
2) Activate by heating at room temperature under vacuum for 20 hours before use
Other Features
Fluorescence: NA
Applications
1) Efficient separation of CH4/N2 mixtures for coal-bed methane purification.
2) Potential use in industrial gas separation and purification processes.
Characterizations
References
1) Shao-Min Wang, Mohana Shivanna, Qing-Yuan Yang; Angew. Chem. Int. Ed. 2022, 61, e202201017, DOI: 10.1002/anie.202201017 ; Nickel-Based Metal–Organic Frameworks for Coal-Bed Methane Purification with Record CH4/N2 Selectivity