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4,5,9,10-Pyrenetetrone, 2,7-bis(1,1-dimethylethyl)-
4,5,9,10-Pyrenetetrone, 2,7-bis(1,1-dimethylethyl)-
CAS:190843-93-7 M.F.:C24H22O4 M.W.:374.42908
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Product Name:2,​7-​tert-​butyl-​4,​5,​9,​10-​tetraketone
Synonymous:2,7-bis(1,1-dimethylethyl)-4,5,9,10-Pyrenetetrone ; tert-butylpyrene tetraone
CAS:190843-93-7
Basic Info
M.F.  C24H22O4 M.W.  374.42908
Appearance  
Properties
1)  It is soluble in DMF, DMSO, etc.
2)  Sealed at room temperature
Appications
1) It can be used as a monomer for the synthesis of COF material, inlcuding: LZU-​501 [r1]; MPc-pz COF (M = Zn, Cu) [r2] ; CS-COF [r3]
2) It can be used as an intermediate for optoelectronic materials
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Wang, P.; Ding, S.; Zhang, Z.; Wang, Z.; Wang, W.; J. Am. Chem. Soc. 2019, 141, 45, 18004-18008, DOI: 10.1021/jacs.9b10625 ; Constructing Robust Covalent Organic Frameworks via Multicomponent Reactions 
2) Wang, M.; Ballabio, M.; Wang, M.; Lin, H.; Biswal, B.; Han, X.; Paasch, S.; Brunner, E.; Liu, P.; Chen, M.; Bonn, M.; Heine, T.; Zhou, S.; Canovas, E.; Dong, R.; Feng, X.; J. Am. Chem. Soc. 2019, 141(42), 16810-16816, DOI: 10.1021/jacs.9b07644 ; Unveiling Electronic Properties in Metal–Phthalocyanine-Based Pyrazine-Linked Conjugated Two-Dimensional Covalent Organic Frameworks 
3) Guo, J.; Xu, Y.; Jin, S.; Chen, L.; Kaji, T.; Honsho, Y.; Addicoat, M.; Kim, J.; Saeki, A.; Ihee, H.; Seki, S.; Irle, S.; Hiramoto, M.; Gao, J.; Jiang, D.; Nat. Commun. 2013, 4, 3736/1-3736/8, DOI: 10.1038/ncomms3736
4) Kohl, B.; Rominger, F.; Mastalerz, M.; Angew. Chem., Int. Ed. 2015, 54(20), 6051-6056, DOI: 10.1002/anie.201411972
5) Gao, B.; Wang, M.; Cheng, Y.; Wang, L.; Jing, X.; Wang, F.;  J. Am. Chem. Soc. 2008, 130(26), 8297-8306, DOI: 10.1021/ja800311a
6) Hu, J.; Zhang, D.; Harris, F.; J. Org. Chem 2005, 70(2), 707-708, DOI: 10.1021/jo048509q
190843-93-7-CS014252.pdf Download
190843-93-7-CS014568.pdf Download
190843-93-7-CS014686.pdf Download
190843-93-7-CS017131.pdf Download
4,5,9,10-Pyrenetetrone, 2,7-bis(1,1-dimethylethyl)-
4,5,9,10-Pyrenetetrone, 2,7-bis(1,1-dimethylethyl)-

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