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1,4-Benzenedicarboxaldehyde, 2,5-dimethoxy-, polymer with 5'-(4-aminophenyl)[1,1':3',1''-terphenyl]-4,4''-diamine
1,4-Benzenedicarboxaldehyde, 2,5-dimethoxy-, polymer with 5'-(4-aminophenyl)[1,1':3',1''-terphenyl]-4,4''-diamine
CAS:1897438-56-0
M.F.:(C24H21N3.C10H10O4)X
M.W.:545.63
Pricing
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Product: TPB-DMTP-COF
Synonyms:TAPB-DMTP-COF；1,4-Benzenedicarboxaldehyde, 2,5-dimethoxy-, polymer with 5'-(4-aminophenyl)[1,1':3',1''-terphenyl]-4,4''-diamine
CAS：1897438-56-0
Basic Information
| Unit MF. | C24H21N3.C10H10O4 | Unit MW. | 545.63 | ||
| Linkers |
1)2,5-Dimethoxyterephthalaldehyde （CAS: 7310-97-6） 2) 1,3,5-Tris(4-aminophenyl)benzene (CAS:118727-34-7) |
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| Aperture | 3.26 nm | Pore volume | 1.34 cm³/g | ||
| Surface Area | BET比表面积≥1500m²/g | ||||
| Analog Structure |   |
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Product Property
| Appearance |  |
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| Particle Size | / | |||
Stability
1) It showed thermal stability of up to 400 ° C through thermogravimetric analysis (TGA) under a nitrogen atmosphere. After soaking in water, various organic solvents, 12 M HCl, and 14 M NaOH solvents for one week, the original crystallinity and porosity were maintained.
Preservation
1) Dry and sealed under normal temperature or low temperature conditions
2) It is recommended to activate for 12 hours at120 degree in vacuum before gas adsorption test
2) It is recommended to activate for 12 hours at120 degree in vacuum before gas adsorption test
Other Features
Fluorescence:NA
Applications
1) A one-dimensional mesoporous channel with hexagonal arrangement, similar to a biological ion channel, is conducive to ion conduction;
2) As a proton conducting material, it may have potential applications in fields such as fuel cells, electrochemical sensors, electrochemical reactors, and electrochromic devices;
3) Its high crystallinity, good porosity, and excellent stability may also have application prospects in gas adsorption and separation, heterogeneous catalysis, and other fields.
Characterizations
References
1）Hong Xu, Shanshan Tao and Donglin Jiang; Nature Mater 15, 722–726 2016 ; DOI：10.1038/nmat4611; Proton conduction in crystalline and porous covalent organic frameworks；【文献解读】
2）Normanda Brown, Qingsong Zhang, Ziad Alsudairy, Chaochao Dun, Yogendra Nailwal, Allea Campbell, Chelsea Harrod, Linfeng Chen, Spirit Williams, Jeffrey J. Urban, Yi Liu, and Xinle Li*; ACS Sustainable Chem. Eng. 2024; DOI：10.1021/acssuschemeng.4c04003; Mechanochemical in Situ Encapsulation of Palladium in Covalent Organic Frameworks；文献解读