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T-COF
T-COF
CAS:1883264-97-8
M.F.:C21H18N6.C9H6O3
M.W.:516.54996
Pricing
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Product: T-COF
Synonyms:PI-3-COF;N-COF
CAS：1883264-97-8
Basic Information
| Unit MF. | C21H18N6.C9H6O3 | Unit MW. | 516.54996 | ||
| Linkers |
1) 1,3,5-tris-(4-aminophenyl)triazine（CAS: 14544-47-9） 2) Benzene-1,3,5-Tricarbaldehyde (CAS:3163-76-6 ) |
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| Aperture | 1.1 nm | Pore volume | 0.84 cm³/g | ||
| Surface Area | BET比表面1000 -1700m²/g | ||||
| Analog Structure |  |
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Product Property
| Appearance | yellow solid |  |
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| Particle Size | 50 nm | |||
Stability
1) The thermal decomposition temperature is about 450℃
Preservation
1) Dry and sealed under normal temperature or low temperature conditions
2) It is recommended to activate for 12 hours at 120 degree in vacuum before gas adsorption test
2) It is recommended to activate for 12 hours at 120 degree in vacuum before gas adsorption test
Other Features
Fluorescence:NA
Applications
1) It can be used for selective gas capture and separation, such as CO2 capture;
2) The imine group has Lewis alkalinity and can be used as a catalyst or catalyst carrier for various chemical reactions, including redox reactions, C-C coupling reactions, and photocatalytic reactions;
3) It can serve as a carrier for drug molecules, used for targeted drug delivery and controlled release;
4) It can be used for water treatment and pollutant adsorption, such as removing heavy metal ions and organic pollutants from water;
Characterizations
References
1) Qiang Gao, Linyi Bai, Xiaojing Zhang, Peng Wang, Peizhou Li, Yongfei Zeng, Ruqiang Zou, and Yanli Zhao；Chin. J. Chem. 2015, 33, 90—94；DOI: 10.1002/cjoc.201400550；Synthesis of Microporous Nitrogen-Rich Covalent-Organic Framework and Its Application in CO2 Capture;
2) Linyi Bai, Soo Zeng Fiona Phua, Wei Qi Lim, Avijit Jana, Zhong Luo, Huijun Phoebe Tham, Lingzhi Zhao, Qiang Gao, Yanli Zhao*；J. Name., 2013, 00, 1-3 | 1；DOI: 10.1039/x0xx00000x；Nanoscale Covalent Organic Frameworks as Smart Carriers for Drug Delivery；
3) Jian-Guo Fu, Li-Xia Xie, Jun Du, Zhenhua Xu, Zhi-Qiang Shi,* Li-Fen Hou,* and Gang Li*; ACS Sustainable Chem. Eng. 2024; DOI：10.1021/acssuschemeng.4c04144; Green and Efficient Syntheses of a Series of Imine-Connected Covalent Organic Frameworks in Acetic Acid Solution; 文献解读