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TpBPy
TpBPy
CAS:1879089-19-6
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Product：TpBpy COF
Synonyms：1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy-, polymer with [2,2′-bipyridine]-5,5′-diamine
CAS：1879089-19-6
Synonyms：1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy-, polymer with [2,2′-bipyridine]-5,5′-diamine
CAS：1879089-19-6
Basic Information
| Unit MF. | C10H10N4.C9H6O6 | Unit MW. | 396.35 | ||
| Linkers |
2,4,6-trihydroxy-1,3,5-benzenetricarbaldehyde (CAS:34374-88-4); [2,2′-Bipyridine]-5,5′-diamine (CAS: 52382-48-6) |
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| Aperture | 1.8nm | Pore volume | 0.087 cm3/g | ||
| Surface Area | BET Specific surface 400-600 m2/g | ||||
| Analog Structure | |||||
Product Property
| Appearance |
Dark Red or brown solid |
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| Particle Size | irregular particle clusters | |||
Stability
1) Stable in aqueous solution and acidic solutions, unstable under strong alkaline conditions
Preservation
1) Dry and sealed under normal temperature or low temperature conditions
Other Features
Fluorescence: NA
Applications
1) For gas and pollutant adsorption
2) Rigid pores and complex sites of bipyridine groups is potential to load other metal catalysts
2) Rigid pores and complex sites of bipyridine groups is potential to load other metal catalysts
Characterizations
References
1) Shinde, Digambar Balaji; Aiyappa, Harshitha Barike; Bhadra, Mohitosh; Biswal, Bishnu P.; Wadge, Pritish; Kandambeth, Sharath; Garai, Bikash; Kundu, Tanay; Kurungot, Sreekumar; Banerjee, Rahul
Journal of Materials Chemistry A 2016, 4(7), 2682-2690, DOI: 10.1039/c5ta10521h ; A mechanochemically synthesized covalent organic framework as a proton-conducting solid electrolyte
2) Sun, Qi; Aguila, Briana; Perman, Jason; Nguyen, Nicholas; Ma, Shengqian; Journal of the American Chemical Society 2016, 138(48), 15790-15796, DOI: 10.1021/jacs.6b10629 ; Flexibility Matters: Cooperative Active Sites in Covalent Organic Framework and Threaded Ionic Polymer
3) Sasmal, Himadri Sekhar; Aiyappa, Harshitha Barike; Bhange, Siddheshwar N.; Karak, Suvendu; Halder, Arjun; Kurungot, Sreekumar; Banerjee, Rahul; Angewandte Chemie, International Edition 2018, 57(34), 10894-10898, DOI: 10.1002/anie.201804753 ; Superprotonic Conductivity in Flexible Porous Covalent Organic Framework Membranes
4) Zhong, Wanfu; Sa, Rongjian; Li, Liuyi ; He, Yajun; Li, Lingyun ; Bi, Jinhong ; Zhuang, Zanyong ; Yu, Yan ; Zou, Zhigang; Journal of the American Chemical Society 2019, 141(18), 7615-7621, DOI: 10.1021/jacs.9b02997 ; A Covalent Organic Framework Bearing Single Ni Sites as a Synergistic Photocatalyst for Selective Photoreduction of CO2 to CO
5) Peng Gao, Yezi Hu, Zewen Shen, Guixia Zhao, Ruiqing Cai, Feng Chu, Zhuoyu Ji, Xiangke Wang & Xiubing Huang; Nat Commun 15, 6700 2024 ; DOI：10.1038/s41467-024-50951-4;Ultra-highly efficient enrichment of uranium from seawater via studtite nanodots growth-elution cycle; 文献解读
6) Islam E. Khalil, Prasenjit Das, Hüseyin Küçükkeçeci, Veit Dippold, Jabor Rabeah, Warisha Tahir, Jérôme Roeser, Johannes Schmidt, and Arne Thomas*; Chem. Mater. 2024; DOI：10.1021/acs.chemmater.4c01298; Hierarchical Porous Covalent Organic Frameworks: The Influence of Additional Macropores on Photocatalytic Hydrogen Evolution and Hydrogen Peroxide Production;文献解读