NH2-UIO-66(Hf)
NH2-UIO-66(Hf)
CAS:1848255-42-4
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Product: NH2-UIO-66(Hf)
Synonyms: NA
CAS：1848255-42-4
Basic Information
| Unit MF. | C48H34N6O32Hf6 | Unit MW. | 2248.51 | ||
| Coordination Metal | Hf | Linkers | 2-aminoterephthalic acid（CAS：10312-55-7） | ||
| Pore Size | 0.8nm; 1.1nm | Pore volume | 0.5 cm3/g | ||
| Surface Area | BET Specific surface 600- 800 m2/g | ||||
| Analog Structure |   |
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Product Property
| Appearance | Yellowish Powder |  |
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| Particle Size | 100-300nm clusters | |||
Stability
1) NH2-UIO-66 is stable in air, stable in aqueous and acidic conditions(stable in PH 1-12)
2）High thermal stability, thermal decomposition temperature above 400 ° C
2）High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 6 hours at 120 degree in vacuum.
Other Features
Fluorescence: λem=456nm
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) NH2-UIO-66 has rigid framework, the amino group could be post-modified without destroying the framework of the material
2) NH2-UIO-66 has rigid framework, the amino group could be post-modified without destroying the framework of the material
Characterizations
References
1) Li, Liangsha; Wang, Keke; Huang, Hongliang; Yang, Qingyuan; Zhang, Yi; Wang, Shaohua; Wu, Pingyi; Lan, Ling; Liu, Dahuan; Zhong, Chongli, Huagong Xuebao (Chinese Edition) (2014), 65(5), 1706-1715, DOI: 10.3969/j.issn.0438-1157.2014.05.021 ; Synthesis of exceptional stable Hf-based metal-organic frameworks: characterization, stability and CO2 adsorption performance（高稳定铪金属-有机骨架材料的合成及二氧化碳捕获性能）
2）By: Marshall, Ross J.; Hobday, Claire L.; Murphie, Colin F.; Griffin, Sarah L.; Morrison, Carole A.; Moggach, Stephen A.; Forgan, Ross S., J Mater. Chem. A 2016, 4(18), 6955-69630, DOI: 10.1039/c5ta10401g ; Amino acids as highly efficient modulators for single crystals of zirconium and hafnium metal-organic frameworks
3) Hu, Zhigang; Nalaparaju, Anjaiah; Peng, Yongwu; Jiang, Jianwen; Zhao, Dan, Inorg. Chem. 2016, 55(3), 1134-1141, DOI: 10.1021/acs.inorgchem.5b02312 ; Modulated Hydrothermal Synthesis of UiO-66(Hf)-Type Metal-Organic Frameworks for Optimal Carbon Dioxide Separation