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CAS:1842361-23-2 M.F.:C22H16N2O8F4Zn2 M.W.:643.14464
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Product: FDMOF-2
Synonyms: NA
CAS:1842361-23-2 

Basic Information
Unit MF. C22H16N2O8F4Zn2 Unit MW. 643.14464
Coordination Metal Zn Linkers

2,5-bis(trifluoromethyl)terephthalic acid (BDC-(CF3)2)

Pore Size ~5.1 Å Pore Volume 0.42 cm3/g
Surface Area 1011 m2/g
Analog Structure /
Product Property
Appearance Cuboid  
Particle Size Not explicitly provided, but the particle size increases compared to FDMOF-1
Stability
1) Stable in 40% and 70% relative humidity conditions for up to 6 months. No changes in PXRD patterns and minimal changes in N2 adsorption isotherms.
2) Thermal decomposition temperature is above 673 K.
Preservation
1) Store in a dry and cool condition.
2) Activate by heating at room temperature under vacuum for 3 hours.
Other Features
NA
Applications
1) Efficient separation of propane/propylene (C3H8/C3H6) mixtures, even under high humidity conditions, producing high-purity propylene.
2) High adsorption capacity and selectivity for C3H8.
Characterizations
XRD
NA
SEM
NA
BET
NA
FTIR
NA
References
1) Yong Wang, Tong Li, Libo Li, Rui-Biao Lin, Xiaoxia Jia, Zeyu Chang, Hui-Min Wen, Xiao-Ming Chen, Jinping Li; Adv. Mater., 2023, 35, 2207955, DOI: 10.1002/adma.202207955; Construction of Fluorinated Propane-Trap in Metal–Organic Frameworks for Record Polymer-Grade Propylene Production under High Humidity Conditions

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