Product: FDMOF-2
Synonyms: NA
CAS:1842361-23-2
Basic Information
Unit MF. |
C22H16N2O8F4Zn2 |
Unit MW. |
643.14464 |
Coordination Metal |
Zn |
Linkers |
2,5-bis(trifluoromethyl)terephthalic acid (BDC-(CF3)2)
|
Pore Size |
~5.1 Å |
Pore Volume |
0.42 cm3/g |
Surface Area |
1011 m2/g |
Analog Structure |
/ |
Product Property
Appearance |
Cuboid |
|
Particle Size |
Not explicitly provided, but the particle size increases compared to FDMOF-1 |
Stability
1) Stable in 40% and 70% relative humidity conditions for up to 6 months. No changes in PXRD patterns and minimal changes in N2 adsorption isotherms.
2) Thermal decomposition temperature is above 673 K.
Preservation
1) Store in a dry and cool condition.
2) Activate by heating at room temperature under vacuum for 3 hours.
Other Features
NA
Applications
1) Efficient separation of propane/propylene (C3H8/C3H6) mixtures, even under high humidity conditions, producing high-purity propylene.
2) High adsorption capacity and selectivity for C3H8.
Characterizations
References
1) Yong Wang, Tong Li, Libo Li, Rui-Biao Lin, Xiaoxia Jia, Zeyu Chang, Hui-Min Wen, Xiao-Ming Chen, Jinping Li; Adv. Mater., 2023, 35, 2207955, DOI: 10.1002/adma.202207955; Construction of Fluorinated Propane-Trap in Metal–Organic Frameworks for Record Polymer-Grade Propylene Production under High Humidity Conditions