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2,3,6,7,10,11-Hexakis(4-carboxyphenyl)triphenylene
2,3,6,7,10,11-Hexakis(4-carboxyphenyl)triphenylene
CAS:1821122-35-3 M.F.:C60H36O12 M.W.:948.9207
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Product Name:4,​4',​4'',​4''',​4'''',​4'''''-​(2,​3,​6,​7,​10,​11-​triphenylenehexayl)​hexakisBenzoic acid,
Synonymous:TP ; H6TPHB;Benzoic acid, 4,​4',​4'',​4''',​4'''',​4'''''-​(2,​3,​6,​7,​10,​11-​triphenylenehexayl)​hexakis-
CAS:1821122-35-3
Basic Info
M.F. C60H36O12 M.W. 948.92064
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:hydrogen-​bonded hexagonal network (H-​HexNet): Tp-1 [r2]; BUT-46A-F [r3]
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Hisaki, Ichiro; Ikenaka, Nobuaki; Tohnai, Norimitsu; Miyata, Mikiji; Chemical Communications 2016, 52(2), 300-303, DOI: 10.1039/C5CC07690K ; Polymorphs of layered assemblies of hydrogen-​bonded hexagonal networks caused by conformational frustration
2) Hisaki, Ichiro; Nakagawa, Shoichi; Ikenaka, Nobuaki; Imamura, Yutaka; Katouda, Michio; Tashiro, Motomichi; Tsuchida, Hiromu; Ogoshi, Tomoki; Sato, Hiroyasu; Tohnai, Norimitsu; Miyata, Mikiji; DOI: 10.1021/jacs.6b02968 ; A Series of Layered Assemblies of Hydrogen-​Bonded, Hexagonal Networks of C3-​Symmetric π-​Conjugated Molecules: A Potential Motif of Porous Organic Materials
3) Zhang, Yong-Zheng; He, Tao; Kong, Xiang-Jing; Lv, Xiu-Liang; Wu, Xue-Qian; Li, Jian-Rong; ACS Applied Materials & Interfaces 2018, 10(33), 27868-27874, DOI: 10.1021/acsami.8b09333 ; Tuning Water Sorption in Highly Stable Zr(IV)​-​Metal-​Organic Frameworks through Local Functionalization of Metal Clusters
4) Dai, Hongliang; Wang, Shuai; Hisaki, Ichiro; Nakagawa, Shoichi; Ikenaka, Nobuaki; Deng, Ke; Xiao, Xunwen; Zeng, Qingdao; Chemistry - An Asian Journal (2017), 12(19), 2558-2564, DOI: 10.1002/asia.201700749 ; On-​Surface Self-​Assembly of a C3-​Symmetric π-​Conjugated Molecule Family Studied by STM: Two-​Dimensional Nanoporous Frameworks
2,3,6,7,10,11-Hexakis(4-carboxyphenyl)triphenylene
2,3,6,7,10,11-Hexakis(4-carboxyphenyl)triphenylene

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