Al-bttotb
Al-bttotb
CAS:1818266-93-1
M.F.:C54H33Al3O21.C3H7NO.H2O
M.W.:1189.88
Pricing
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Product: 467-MOF(Al)
Synonyms: Al-bttotb; [Al3(BTTB)2(OH)3](DMF)5.5(H2O)3
CAS：1818266-93-1
Basic Information
| Unit MF. | C54H30O21Al3.C3H7NO | Unit MW. | 1168.84168 | ||
| Coordination Metal | Al | Linkers | 4,4',4''-(benzene-1,3,5-triyltris(oxy))tribenzoic acid (CAS: 1071125-59-1) | ||
| Pore Size | 2D Channel: 0.4*0.5 / 0.5*0.6 | Pore volume | 0.46 cm3/g | ||
| Surface Area | BET Specific surface 700 m2/g, | ||||
| Analog Structure |   |
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Product Property
| Appearance | Colorless Crystals | |||
| Particle Size | 300-600nm | |||
Stability
1) 467-MOF / Al-bttotb is stable in air, stable in air at 150 ° for 1 week; thermal decomposition temperature above 350 ° C
2) 467-MOF / Al-bttotb is stable in air aqueous conditions(even in boiling water for more than 1 week) , stable in PH 1-11 for more than 24 hours. It is stable in common organic solvents (e.g. DMF, THF, ethanol)
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 6 hours at 120 degree in vacuum.
2) It is recommended to activate for 6 hours at 120 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) 467-MOF/Al-bttotb has rigid micropores, which is potential for the separation of Alkane Isomers
2) 467-MOF/Al-bttotb has rigid micropores, which is potential for the separation of Alkane Isomers
Characterizations
References
1) Z. Wang, M. Chen, C. Liu, X. Wang, H. Zhao, M. Du, Chem. Eur. J. 2015, 21, 17215-17219, DOI : 10.1002/chem.201502615 ; A Versatile AlIII‐Based Metal–Organic Framework with High Physicochemical Stability
2) L. Yu, X. Dong, Q. Gong, S. Acharya, Y. Lin, H. Wang, Y. Han, T. Thonhauser, J. Li, J. Am. Chem. Soc. 2020, 142, 15, 6925-6929, DOI: 10.1021/jacs.0c01769 ; Splitting Mono- and Dibranched Alkane Isomers by a Robust Aluminum-Based Metal–Organic Framework Material with Optimal Pore Dimensions