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TFP-DABA
TFP-DABA
CAS:1809912-53-5 M.F.:C9H6O6.C6H8N2O3S M.W.:398.34466
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ProductNUS-9
Synonyms:TFP-DABA;Benzenesulfonic acid, 2,5-diamino-, polymer with 2,4,6-trihydroxy-1,3,5-benzenetricarboxaldehyde 
CAS:1809912-53-5
Basic Information
Unit MF. (C9H6O6.C6H8N2O3S)x Unit MW. 398.35
Linkers

1) 2,4,6-trihydroxy-1,3,5-benzenetricarbaldehyde (CAS:34374-88-4);

2) 2,5-Diaminobenzenesulfonic acid (CAS:88-45-9)

Aperture 1.4nm Pore volume 0.48 cm3/g
Surface Area  
Analog Structure
Product Property
Appearance

Red or dark orange solid

 
Particle Size  50至100纳米
Stability
1)  TFP-DABA exhibits thermal stability up to 250 ° C in thermogravimetric analysis (TGA)
Preservation
1) It is recommended to store it in a dry and cool place and seal it to avoid direct contact with moisture and dampness.
2) Before catalytic reaction, it is recommended to vacuum dry at 150 ° C for 12 hours to remove adsorbed moisture and solvent.
Other Features
Fluorescence: NA
Applications
1) Used for gas and pollutant adsorption
2) As a solid acid catalyst, especially in the conversion of biomass based chemicals, it exhibits excellent catalytic activity and chemical selectivity.
3) Due to its high catalytic activity and good recyclability, TFP-DABA has potential application value in the fields of fine chemical synthesis, fuel production, and other biobased chemical synthesis.
Characterizations
XRD
 
SEM
 
BET
 
FTIR
NA
References
 
1) Yongwu Peng, Zhigang Hu, Yongjun Gao, Daqiang Yuan, Zixi Kang, Yuhong Qian, Ning Yan, and Dan Zhao*; ChemSusChem 2015, 8, 3208 – 3212; DOI:10.1002/cssc.201500755; Synthesis of a Sulfonated Two-Dimensional Covalent Organic Framework as an Efficient Solid Acid Catalyst for Biobased Chemical Conversion;
2)Wenqiao Meng, Qiang Xue, Jinyuan Zhu & Kaisong Zhang; npj Clean Water 7, 23, 2024; 10.1038/s41545-024-00320-x; Exploiting sulfonated covalent organic frameworks to fabricate long-lasting stability and chlorine-resistant thin-film nanocomposite nanofiltration membrane Check for updates;
3) Jingyu Du, Xiao Zhan, Yuhuan Xu, Daohai Zhang,* and Shuhao Qin*; Nano Lett. 2024, 24, 43, 13592–13599; DOI:10.1021/acs.nanolett.4c03227; Heat-Resistant Covalent Organic Framework (COF) PVA-Hybridized Gel Electrolyte for the Preparation of Dendrite-Free Zinc-Ion Batteries;

 4) Valle Krishnaveni, Marilyn Esclance DMello, Nany Thokala, Alekhya Bonda, Vinay Kumar Sriramadasu, Swamy Akkenapally, Sumit B. Bubanale, Keloth Basavaiah, Santanu Bhattacharyya, and Suresh Babu Kalidindi*; ACS Appl. Nano Mater. 2024, 7, 20, 23416–23422; DOI:10.1021/acsanm.4c04609; Catalytic Gas-Driven Exfoliation of Sulfonic Acid-Linked Covalent Organic Framework Nanostructures for Hydrogen Sensing

TFP-DABA
TFP-DABA

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