Product:NUS-9Synonyms:TFP-DABA;Benzenesulfonic acid, 2,5-diamino-, polymer with 2,4,6-trihydroxy-1,3,5-benzenetricarboxaldehyde CAS:1809912-53-5
Basic Information
Unit MF. |
(C9H6O6.C6H8N2O3S)x |
Unit MW. |
398.35 |
Linkers |
1) 2,4,6-trihydroxy-1,3,5-benzenetricarbaldehyde (CAS:34374-88-4);
2) 2,5-Diaminobenzenesulfonic acid (CAS:88-45-9)
|
Aperture |
1.4nm |
Pore volume |
0.48 cm3/g |
Surface Area |
|
Analog Structure |
 |
Product Property
Appearance |
Red or dark orange solid
|
|
Particle Size |
50至100纳米 |
Stability
1) TFP-DABA exhibits thermal stability up to 250 ° C in thermogravimetric analysis (TGA)
Preservation
1) It is recommended to store it in a dry and cool place and seal it to avoid direct contact with moisture and dampness.
2) Before catalytic reaction, it is recommended to vacuum dry at 150 ° C for 12 hours to remove adsorbed moisture and solvent.
Other Features
Fluorescence: NA
Applications
1) Used for gas and pollutant adsorption
2) As a solid acid catalyst, especially in the conversion of biomass based chemicals, it exhibits excellent catalytic activity and chemical selectivity.
3) Due to its high catalytic activity and good recyclability, TFP-DABA has potential application value in the fields of fine chemical synthesis, fuel production, and other biobased chemical synthesis.
Characterizations
1) Yongwu Peng, Zhigang Hu, Yongjun Gao, Daqiang Yuan, Zixi Kang, Yuhong Qian, Ning Yan, and Dan Zhao*; ChemSusChem 2015, 8, 3208 – 3212; DOI:10.1002/cssc.201500755; Synthesis of a Sulfonated Two-Dimensional Covalent Organic Framework as an Efficient Solid Acid Catalyst for Biobased Chemical Conversion;
2)Wenqiao Meng, Qiang Xue, Jinyuan Zhu & Kaisong Zhang; npj Clean Water 7, 23, 2024; 10.1038/s41545-024-00320-x; Exploiting sulfonated covalent organic frameworks to fabricate long-lasting stability and chlorine-resistant thin-film nanocomposite nanofiltration membrane Check for updates;
3) Jingyu Du, Xiao Zhan, Yuhuan Xu, Daohai Zhang,* and Shuhao Qin*; Nano Lett. 2024, 24, 43, 13592–13599; DOI:10.1021/acs.nanolett.4c03227; Heat-Resistant Covalent Organic Framework (COF) PVA-Hybridized Gel Electrolyte for the Preparation of Dendrite-Free Zinc-Ion Batteries;
4) Valle Krishnaveni, Marilyn Esclance DMello, Nany Thokala, Alekhya Bonda, Vinay Kumar Sriramadasu, Swamy Akkenapally, Sumit B. Bubanale, Keloth Basavaiah, Santanu Bhattacharyya, and Suresh Babu Kalidindi*; ACS Appl. Nano Mater. 2024, 7, 20, 23416–23422; DOI:10.1021/acsanm.4c04609; Catalytic Gas-Driven Exfoliation of Sulfonic Acid-Linked Covalent Organic Framework Nanostructures for Hydrogen Sensing