Product: UIO-66(Ce)
Synonyms: Ce-UIO-66-BDC
CAS:1801427-51-9
Basic Information
Unit MF. |
C48H4O32Ce6 |
Unit MW. |
1953.38 |
Coordination Metal |
Ce |
Linkers |
Terephthalic acid (CAS: 100-21-0) |
Pore Size |
0.8nm; 1.1nm |
Pore volume |
0.5 cm3/g |
Surface Area |
BET Specific surface 1100 m2/g, |
Analog Structure |
|
Product Property
Appearance |
Pale Yellow Powders |
 |
Particle Size |
50-200nm irregular nanoparticles |
Stability
1) Ce-UIO-66 is stable in air, stable in aqueous and acidic conditions(stable in PH 1-12)
2) High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption; UIO-66 has very rigid framework, which is good carrier of catalyst.
2) With special oxidation and reduction property of Ce+/Ce2+, Ce-UIO-66 could be used to catalyze oxidation reaction
Characterizations
References
1) Lammert, Martin; Wharmby, Michael T.; Smolders, Simon; Bueken, Bart; Lieb, Alexandra; Lomachenko, Kirill A.; Vos, Dirk De; Stock, Norbert; Chem. Commun. 2015, 51(63), 12578-12581, DOI: 10.1039/C5CC02606G ; Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity