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9,9'-Spirobi[9H-fluorene]-3,3',6,6'-tetracarboxaldehyde, 2,2',7,7'-tetramethoxy-
9,9'-Spirobi[9H-fluorene]-3,3',6,6'-tetracarboxaldehyde, 2,2',7,7'-tetramethoxy-
CAS:1801236-33-8 M.F.:C33H24O8 M.W.:548.53886
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Product Name:2,2′,7,7′-tetramethoxy-9,9′-spirobi[fluorene]-3,3′,6,6′-tetracarbaldehyde
Synonymous:TMSFTA;9,​9'-​Spirobi[9H-​fluorene]​-​3,​3',​6,​6'-​tetracarboxaldehyde, 2,​2',​7,​7'-​tetramethoxy-
CAS:1801236-33-8
Basic Info
M.F. C33H24O8 M.W. 548.53886
Appearance  
Properties
1)   It is soluble in DCM,DMF,DMSO,etc.
2)   Sealed storage at 2-8 ℃ temperature
Appications
1) It could be used as monomer linker for COF synthesis:COF-JCU-550,551,552 [r2]
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Pop, Lidia; Dumitru, Florina; Hadade, Niculina D.; Legrand, Yves-Marie; van der Lee, Arie; Barboiu, Mihail; Grosu, Ion; Org. Lett. 2015), 17(14), 3494-3497, DOI: 10.1021/acs.orglett.5b01576 ; Exclusive Hydrophobic Self-​Assembly of Adaptive Solid-​State Networks of Octasubstituted 9,​9'-​Spirobifluorenes
2) Wang, Yujie; Liu, Yaozu; Li, Hui; Guan, Xinyu; Xue, Ming; Yan, Yushan; Valtchev, Valentin; Qiu, Shilun; Fang, Qianrong; J. Am. Chem. Soc. 2020, 142(8), 3736-3741, DOI: 10.1021/jacs.0c00560 ; Three-​Dimensional Mesoporous Covalent Organic Frameworks through Steric Hindrance Engineering
9,9'-Spirobi[9H-fluorene]-3,3',6,6'-tetracarboxaldehyde, 2,2',7,7'-tetramethoxy-
9,9'-Spirobi[9H-fluorene]-3,3',6,6'-tetracarboxaldehyde, 2,2',7,7'-tetramethoxy-

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