Product: TAPB-TFP
Synonyms: Tp-TAPB-COF
CAS:1800490-22-5
Basic Information
Unit MF. |
C24H21N3.C9H6O6 |
Unit MW. |
561.58398 |
Coordination Metal |
Cu |
Linkers |
1,3,5-tris(4'-aminophenyl)benzene (TAPB) 2,4,6-triformylphloroglucinol (TFP)
|
Pore Size |
~10.5 Å |
Pore Volume |
NA |
Surface Area |
920 m²/g |
Product Property
Stability
1) Stability in solution is not specified in the literature.
Preservation
1) Store in a dry and cool condition.
2) It is recommended to activate the material in a vacuum oven at room temperature for 3 hours before use.
Other Features
Fluorescence: NA
Applications
1) Catalyst for 1,3-dipolar cycloaddition reactions.
2) Potential applications in gas adsorption and separation.
Characterizations
References
1) Romero-Muñiz, Ignacio; Albacete, Pablo; Platero-Prats, Ana E.; Zamora, Félix; ACS Applied Materials & Interfaces 2021, 13, 54106−54112, DOI: 10.1021/acsami.1c18295, Layered Copper-Metallated Covalent Organic Frameworks for Huisgen Reactions;
2)Ignacio Romero-Muñiz, Andreas Mavrandonakis, Pablo Albacete, Alicia Vega, Valérie Briois, Félix Zamora, Ana E. Platero-Prats; Angew. Chem. Int. Ed. 2020, 10.1002/anie.202004197; Unveiling the Local Structure of Palladium Loaded into Imine-Linked Layered Covalent Organic Frameworks for Cross-Coupling Catalysis