Product: H2P-Bph-COF
Synonyms: TAPP-BPDA COF
CAS:1791416-47-1
Basic Information
Unit MF. |
(C44H34N8.C14H10O2)x |
Unit MW. |
885.02 |
Linkers |
1) 5,10,15,20-Tetrakis(4-Aminophenyl)-21H,23H-Porphine (CAS: 22112-84-1)
2) [1,1'-Biphenyl]-4,4'-dicarbaldehyde (CAS:66-98-8 )
|
Aperture |
2.98 nm |
Pore volume |
0.53 cm³/g |
Surface Area |
BET比表面为 550 m²/g |
Analog Structure |
|
Product Property
Appearance |
powder |
|
Particle Size |
/ |
Stability
1) The thermal decomposition temperature is about 400℃
Preservation
1) Dry and sealed under normal temperature or low temperature conditions
2) It is recommended to activate for 12 hours at 120 degree in vacuum before gas adsorption test
Other Features
Fluorescence:NA
Applications
1) It can be used for gas storage and separation;
2) The imine group has Lewis alkalinity and can be used as a catalyst or catalyst carrier for various chemical reactions, including redox reactions, C-C coupling reactions, and photocatalytic reactions;
3) It can serve as a carrier for drug molecules, used for targeted drug delivery and controlled release;
4) It can be used for water treatment and pollutant adsorption, such as removing heavy metal ions and organic pollutants from water;
Characterizations
References
1) Hou, Yuxia; Zhang, Xiaomei; Sun, Junshan; Lin, Sha; Qi, Dongdong; Hong, Runrun; Li, Dianqing; Xiao, Xin; Jiang, Jianzhuang; Microporous and Mesoporous Materials 2015 , 214, 108-114; DOI: 10.1016/j.micromeso.2015.05.002;Good Suzuki-coupling reaction performance of Pd immobilized at the metal-free porphyrin-based covalent organic framework