Tetrakis(4-Ethynylphenyl)Methane
Tetrakis(4-Ethynylphenyl)Methane
CAS:177991-01-4
M.F.:C33H20
M.W.:416.5119
Pricing
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Product Name：tetrakis(4-ethynylphenyl)methane
Synonymous：TEPM
CAS：177991-01-4
Synonymous：TEPM
CAS：177991-01-4
Basic Info
| M.F. | C33H20 | M.W. | 416.5119 | ||
| Appearance | |||||
Properties
1) 177991-01-4 is soluble in DCM、DMF, DMSO, etc.
2) Sealed and stored at 2-8 ℃
2) Sealed and stored at 2-8 ℃
Appications
1) It could be used as monomer linker for COF synthesis:MOF@MON-1–4 [r2]; POP 单体; PAF-25 [r3]; (Graphene Nanoribbon Frameworks) GNF-1-4 [r4]
2）It can be used as a monomer to synthesize polyphenylene dendrimers
Characterization
Reference
1) Wiesler, U.-M.; Berresheim, A. J.; Morgenroth, F.; Lieser, G.; Muellen, K.; Macromolecules 2001, 34(2), 187-199, DOI:10.1021/ma991519m ; Divergent Synthesis of Polyphenylene Dendrimers: The Role of Core and Branching Reagents upon Size and Shape
2) Chun, J.; Kang, S.; Park, N.; Park, E. J.; Jin, X.; Kim, K.-D.; Seo, H. O.; Lee, S. M.; Kim, H. J.; Kwon, W. H.; Park, Y.-K.; Kim, J. M.; Kim, Y. D.; Son, S. U.; J. Am. Chem. Soc. 2014, 136, 6786– 6789, DOI: 10.1021/ja500362w ; Metal–Organic Framework@Microporous Organic Network: Hydrophobic Adsorbents with a Crystalline Inner Porosity
3) Yan, Z.; Yuan, Y.; Tian, Y.; Zhang, D.; Zhu, G.; Angew. Chem., Int. Ed. 2015, 54(43), 12733-12737, DOI: 10.1002/anie.201503362
4) Byun, Y.; Cho, M.; Kim, D.; Jung, Y.; Coskun, A.; Macromolecules 2017, 50(2), 523-533, DOI: 10.1021/acs.macromol.6b02483 ; Edge-Functionalized Graphene Nanoribbon Frameworks for the Capture and Separation of Greenhouse Gases