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PCN-250(Fe)
PCN-250(Fe)
CAS:1771755-22-6 M.F.:C48H28Fe6N6O32 M.W.:1535.83
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Product: PCN-250(Fe) 
Synonyms: MIL-127(Fe); Fe-soc-MOF; PCN-250-(Fe3); Iron azobenzene tetracarboxylic
CAS:1771755-22-6 or 1257379-88-6

Basic Information
Unit MF.  C48H18N6O32Fe6 Unit MW. 1525.774
Coordination  Metal Fe Linkers 3,3’,5,5’-azobenzenetetracarboxylic (CAS:365549-33-3) 
Pore Size 1nm Pore volume 0.5 cm3/g
Surface Area BET Specific surface 1200-1400 m2/g
Analog Structure      
Product Property
Appearance Brown Red Powders  
Particle Size  
Stability
1) PCN-600(Fe) is stable in air, stable in aqueous and acidic conditions(PH2-11)
2) Thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition 
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) Iron-Lewis acid catalyst
Characterizations
XRD
XRD-PCN-250
BET
BET-PCN-250Fe
SEM
SEM-PCN-250
FTIR
FTIR-PCN-250(Fe)
References
1) D. W. Feng, K. C. Wang, Z. W. Wei, Y. P. Chen, C. M. Simon, R. K. Arvapally, R. L. Martin, M. Bosch, T. F. Liu, S. Fordham, D. Q. Yuan, M. A. Omary, M. Haranczyk, B. Smit, H. C. Zhou, Nat. Commun. 2014, 5, 5723. DOI:  10.1038/ncomms6723 (2014) ; Kinetically tuned dimensional augmentation as a versatile synthetic route towards robust metal–organic frameworks
2) A. Dhakshinamoorthy, M.Alvaro, H.Chevreau, P. Horcajada, T.Devic, C. Serre and H. Garcia, Catal. Sci. Technol., 2012,2, 324-330, DOI: 10.1039/C2CY00376G ; Iron(iii) metal–organic frameworks as solid Lewis acids for the isomerization of α-pinene oxide

 

PCN-250(Fe)
PCN-250(Fe)

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