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3,4-Dimethylthieno(2,3-b)thiophene-2,5-dicarboxylic acid
3,4-Dimethylthieno(2,3-b)thiophene-2,5-dicarboxylic acid
CAS:175202-55-8
M.F.:C20H10N4S
M.W.:338.3852
Pricing
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Product Name：3,4-Dimethylthieno[2,3-b]thiophene-2,5-dicarboxylic acid
Synonymous：H2DMTDC
CAS：175202-55-8
Synonymous：H2DMTDC
CAS：175202-55-8
Basic Info
| M.F. | C10H8O4S2 | M.W. | 256.29812 | ||
| Appearance |  |
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Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis：IFMC-27 / IFMC-28 [r1] ; Zr(DMTDC)[r2] ; NENU‐512 [r3] ; Ln(DMTDC)1.5(H2O)2 (Ln = Eu , Tb , Gd , Dy , Er) [r5]; UIO-66(Ce)-DMTDC [r6]
Characterization
Reference
1) Yang, G.; Lang, Z.; Zang, H.; Lan, Y.; He, W.; Zhao, X.; Yan, L.; Wang, X.; Su, Z.; Chem. Commun. 2013, 49(11), 1088-1090, DOI: 10.1039/c2cc36894c ;
Control of interpenetration in S-containing metal–organic frameworks for selective separation of transition metal ions
2) Wang, K.; Huang, H.; Xue, W.; Liu, D.; Zhao, X.; Xiao, Y.; Li, Z.; Yang, Q.; Wang, L.; Zhong, C.; CrystEngComm 2015, 17(19), 3586-3590, DOI: 10.1039/C5CE00269A ; An ultrastable Zr metal-organic framework with a thiophene-type ligand containing methyl groups
3) He, W.; Yang, G.; Tang, Y.; Li, S.; Zhang, S.; Su, Z.; Lan, Y.; Chem.- Eur. J. 2015, 21(27), 9784-9789, DOI: 10.1002/chem.201500815 ; Phenyl Groups Result in the Highest Benzene Storage and Most Efficient Desulfurization in a Series of Isostructural Metal-Organic Frameworks
4) Qin, J.; Du, D.; Li, M.; Lian, X.; Dong, L.; Bosch, M.; Su, Z.; Zhang, Q.; Li, S.; Lan, Y.; Yuan, S.; Zhou, H.; J. Am. Chem. Soc. 2016, 138, 16, 5299-5307, DOI: 10.1021/jacs.6b01093 ; 10.1021/jacs.6b01093 ; Derivation and Decoration of Nets with Trigonal-Prismatic Nodes: A Unique Route to Reticular Synthesis of Metal-Organic Frameworks5) Wang, S.; Cao, T.; Yan, H.; Li, Y.; Lu, J.; Ma, R.; Li, D.; Dou, J.; Bai, J.; Inorg. Chem. 2016, 55(11), 5139-5151, DOI: 10.1021/acs.inorgchem.5b02801 ; Functionalization of Microporous Lanthanide-Based Metal-Organic Frameworks by Dicarboxylate Ligands with Methyl-Substituted Thieno[2,3-b]thiophene Groups: Sensing Activities and Magnetic Properties6) Dalapati, R.; Sakthivel, B.; Ghosalya, M.; Dhakshinamoorthy, A.; Biswas, S.; CrystEngComm 2017, 19(39), 5915-5925, DOI: 10.1039/C7CE01053B ; A cerium-based metal-organic framework having inherent oxidase-like activity applicable for colorimetric sensing of biothiols and aerobic oxidation of thiols
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