4,4'-(1,3-dioxo-1,3-propanediyl)bis-Benzonitrile
4,4'-(1,3-dioxo-1,3-propanediyl)bis-Benzonitrile
CAS:166588-20-1
M.F.:C17H10N2O2
M.W.:274.2735
Pricing
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Product Name：4,4′-malonyldibenzonitrile ;
Synonymous：Ph-acac-Ph;4,4'-(1,3-Dioxo-1,3-propanediyl)bis[benzonitrile]; 1,3-Bis(4-cyanophenyl)-1,3-propanedione
CAS：166588-20-1
3) Jena, Himanshu Sekhar; Krishnaraj, Chidharth; Wang, Guangbo; Leus, Karen; Schmidt, Johannes; Chaoui, Nicolas; Van Der Voort, Pascal; Chem. Mater. 2018, 30(12), 4102-4111, DOI: 10.1021/acs.chemmater.8b01409 ; Acetylacetone Covalent Triazine Framework: An Efficient Carbon Capture and Storage Material and a Highly Stable Heterogeneous Catalyst
4) Jena, Himanshu Sekhar; Krishnaraj, Chidharth; Schmidt, Johannes; Leus, Karen; Van Hecke, Kristof; Van Der Voort, Pascal; Chem.- Eur. J. 2020, 26(7), 1548-1557, DOI: 10.1002/chem.201903926 ; Effect of Building Block Transformation in Covalent Triazine-Based Frameworks for Enhanced CO2 Uptake and Metal-Free Heterogeneous Catalysis
Synonymous：Ph-acac-Ph;4,4'-(1,3-Dioxo-1,3-propanediyl)bis[benzonitrile]; 1,3-Bis(4-cyanophenyl)-1,3-propanedione
CAS：166588-20-1
Basic Info
| M.F. | C17H10N2O2 | M.W. | 274.2735 | ||
| Appearance | |||||
Properties
1) It is soluble in DCM,DMF,DMSO,etc.
2) Sealed storage at 2-8 ℃ temperature
2) Sealed storage at 2-8 ℃ temperature
Appications
1) It could be used as monomer linker for COF synthesis：acac-CTFs [r3]; Pyz-CTF, isox-CTF [r4]
Characterization
Reference
1) Nau, Werner M.; Harrer, Heinrich M.; Adam, Waldemar; Journal of the American Chemical Society 1994, 116(24), 10972-10982; DOI: 10.1021/ja00103a012 ; Radical Stabilization and Ground State Polar Substituent Effects in the Thermal Decomposition of Azoalkanes
2) Carlucci, Lucia; Ciani, Gianfranco; Maggini, Simona; Proserpio, Davide M.; Visconti, Marco; Chem.-Eur. J. 2010, 16(41), 12328-12341, DOI: 10.1002/chem.201001256 ; Heterometallic Modular Metal-Organic 3D Frameworks Assembled via New Tris-β-Diketonate Metalloligands: nanoporous Materials for Anion Exchange and Scaffolding of Selected Anionic Guests