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TAPB-BTCA COF
TAPB-BTCA COF
CAS:1648559-39-0
M.F.:C24H21N3.C9H6O3
M.W.:513.58578
Pricing
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Product: RT-COF-1
Synonyms:TAPB-BTCA COF;TB-COF
CAS：1648559-39-0
Basic Information
| Unit MF. | (C24H21N3.C9H6O3)x | Unit MW. | 513.59 | ||
| Linkers |
1) 1,3,5-Tris(4-aminophenyl)benzene（CAS: 118727-34-7） 2) Benzene-1,3,5-Tricarbaldehyde (CAS:3163-76-6 ) |
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| Aperture | 11.9 Å | Pore volume | 0.224 cm3/g | ||
| Surface Area | BET比表面 | ||||
| Analog Structure | |||||
Product Property
| Appearance | powder | |||
| Particle Size | / | |||
Stability
1) The thermal decomposition temperature is about 450℃
Preservation
1) Dry and sealed under normal temperature or low temperature conditions
2) It is recommended to activate for 12 hours at 120 degree in vacuum before gas adsorption test
2) It is recommended to activate for 12 hours at 120 degree in vacuum before gas adsorption test
Other Features
Fluorescence:NA
Applications
1) It can be used for gas storage and separation;
2) The imine group has Lewis alkalinity and can be used as a catalyst or catalyst carrier for various chemical reactions, including redox reactions, C-C coupling reactions, and photocatalytic reactions;
3) It can serve as a carrier for drug molecules, used for targeted drug delivery and controlled release;
4) It can be used for water treatment and pollutant adsorption, such as removing heavy metal ions and organic pollutants from water;
Characterizations
References
1) Ignacio Romero-Muñiz, Pablo Albacete, Ana E. Platero-Prats*, and Félix Zamora*; ACS Appl. Mater. Interfaces 2021, 13, 45; DOI: 10.1021/acsami.1c18295; Layered Copper-Metallated Covalent Organic Frameworks for Huisgen Reactions;
2) Alejandro de la Peña Ruigómez, David Rodríguez-San-Miguel, Dr. Kyriakos C. Stylianou, Dr. Massimiliano Cavallini, Dr. Denis Gentili, Dr. Fabiola Liscio, Prof. Silvia Milita, Dr. Otello Maria Roscioni , Dr. Maria Luisa Ruiz-González, Carlos Carbonell, Prof. Daniel Maspoch, Dr. Rubén Mas-Ballesté, Dr. José Luis Segura, Dr. Félix Zamora; Chemistry - A European Journal 2015 , 21(30), 10666-10670 ; DOI:10.1002/chem.201501692; Direct On-Surface Patterning of a Crystalline Laminar Covalent Organic Framework Synthesized at Room Temperature;
3) Yuting Ma, Shenhui Yu, Wei Li, Di Chen, Zhenqian Zheng, Linjie Mao, Xuan Yang, Wenjun Wang, and Pingwei Liu; Angew. Chem. Int. Ed., 2024, e202416980;DOI：10.1002/anie.202416980;Rapid yet Controlled Synthesis of 2D Covalent Organic Framework Nanocapsules as High-Performance Photocatalytic【文献解读】
4) Kai Xu, Yu Zheng, Junjie Zhou, Yang Zhao, Xiao Pang, Lijuan Cheng, Hui Wang, Xianjuan Zhang, Runnan Zhang,* and Zhongyi Jiang*; Adv. Funct. Mater. 2024, 2417383; DOI: 10.1002/adfm.202417383; Microwave-Assisted Fabrication of Highly Crystalline, Robust COF Membrane for Organic Solvent Nanofiltration