Product: TPB-COF
Synonyms:TFP–TAPB COF
CAS:1644141-15-0
Basic Information
Unit MF. |
(C27H18O3.C24H21N3)x |
Unit MW. |
741.88 |
Linkers |
1) 1,3,5-Tris(4-formylphenyl)benzene (CAS: 118688-53-2)
2) 1,3,5-Tris(4-aminophenyl)benzene (CAS:118727-34-7)
|
Aperture |
1.91 nm |
Pore volume |
0.19 cm3/g |
Surface Area |
BET比表面积为550 m²/g |
Analog Structure |
 |
Product Property
Appearance |
powder |
|
Particle Size |
/ |
Stability
1) Stable at 350-425 ° C, with good chemical stability under acidic and alkaline conditions
Preservation
1) Dry and sealed under normal temperature or low temperature conditions
2) It is recommended to activate for 12 hours at 60 degree in vacuum before gas adsorption test
Other Features
Fluorescence:NA
Applications
1) It can be used for gas storage and separation;
2) It exhibits high activity as a photocatalyst in visible light driven reducing dehalogenation reactions;
3) It can serve as a carrier for drug molecules, used for targeted drug delivery and controlled release;
4) It can be used for water treatment and pollutant adsorption, such as removing heavy metal ions and organic pollutants from water;
Characterizations
References
1) Liu, Haoran; Li, Chunzhi; Li, He ; Ren, Yiqi; Chen, Jian ; Tang, Jianting; Yang, Qihua ;ACS Applied Materials & Interfaces 2020 , 12(18); DOI: 10.1021/acsami.0c00013 ;Structural engineering of two-dimensional covalent organic frameworks for visible-light-driven organic transformations;
2) Zhai, Lipeng; Huang, Ning; Xu, Hong; Chen, Qiuhong; Jiang, Donglin; Chemical Communications (Cambridge, United Kingdom) 2017 , 53(30), 4242-4245 ; DOI: 10.1039/c7cc01921a ; A backbone design principle for covalent organic frameworks: the impact of weakly interacting units on CO2 adsorption;
3) Jian-Guo Fu, Li-Xia Xie, Jun Du, Zhenhua Xu, Zhi-Qiang Shi,* Li-Fen Hou,* and Gang Li*; ACS Sustainable Chem. Eng. 2024; DOI:10.1021/acssuschemeng.4c04144; Green and Efficient Syntheses of a Series of Imine-Connected Covalent Organic Frameworks in Acetic Acid Solution; 【
文献解读】
4) Yuting Ma, Shenhui Yu, Wei Li, Di Chen, Zhenqian Zheng, Linjie Mao, Xuan Yang, Wenjun Wang, and Pingwei Liu; Angew. Chem. Int. Ed., 2024, e202416980;DOI:10.1002/anie.202416980;Rapid yet Controlled Synthesis of 2D Covalent Organic Framework Nanocapsules as High-Performance Photocatalytic【文献解读】