PCN-223
PCN-223
CAS:1640226-29-4
M.F.:C144H82N12O32Zr6
M.W.:3039.59
Pricing
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Product: PCN-223(H)
Synonyms: NA
CAS：1640226-29-4
Basic Information
| Unit MF. | C96H72N8O32Cl2Zr6 | Unit MW. | 3220.84+72 | ||
| Coordination Metal | Zr | Linkers | H2TCPP (CAS: 14609-54-2) | ||
| Pore Size | 1.2 nm | Pore volume | 0.6 cm3/g | ||
| Surface Area | BET Specific surface 1500 m2/g | ||||
| Analog Structure |   |
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Product Property
| Appearance | Dark Purple Powder |  |
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| Particle Size | 500*50nm needle particles | |||
Stability
1) PCN-223 is stable in air, stable in aqueous and acidic conditions(stable in PH 1-11)
2）High thermal stability, thermal decomposition temperature above 400 ° C
2）High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 10 hours at 120 degree in vacuum.
2) It is recommended to activate for 10 hours at 120 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) PCN-223(H or M) is able to convert O2 to singlet oxygen under light condition. It could be used as photocatalyst in organic reaction or as biosensors.
2) PCN-223 has rigid channel framework, which is good carrier of catalyst and poentail material for gas and pollutant adorption.
Characterizations
References
1) D. Feng, Z.-Y. Gu, Y.-P. Chen, J. Park, Z. Wei, Y. Sun, M. Bosch, S. Yuan, and H.-C. Zhou, J. Am. Chem. Soc. 2014, 136, 17714-17717, DOI: 10.1021/ja510525s ; A Highly Stable Porphyrinic Zirconium Metal–Organic Framework with shp-a Topology