Product: ETTA-TP COF
Synonyms:4PE-1P-COF
CAS:1636901-62-6
Basic Information
Unit MF. |
(C26H24N4.C8H6O2)x |
Unit MW. |
526.63 |
Linkers |
1) Tetrakis(4-aminophenyl)ethene(CAS: 78525-34-5)
2) Terephthalaldehyde (CAS:623-27-8)
|
Aperture |
7.1 Å (microporous range) and 26.9 Å (mesoporous range) |
Pore volume |
3.189 cm³/g |
Surface Area |
BET比表面积约为1771.38 m²/g |
Analog Structure |
 |
Product Property
Appearance |
powder |
|
Particle Size |
/ |
Stability
1) It exhibits high stability in aqueous solutions and common organic solvents, and remains stable even after being stored in air for two weeks; Thermogravimetric analysis shows that the weight remains above 95% from 35 ° C to 475 ° C
Preservation
1) Dry and sealed under normal temperature or low temperature conditions
2) It is recommended to activate for 12 hours at 60 degree in vacuum before gas adsorption test
Other Features
Fluorescence:NA
Applications
1) Gas storage, especially in hydrogen adsorption, has shown potential, with a hydrogen adsorption capacity of 1.37 wt% (1 bar, 77 K);
2) Due to its unique dual pore characteristics, it may have applications in adsorption and separation science, such as multi selective gas separation;
3) Its imine group has Lewis alkalinity and can be used as a catalyst or catalyst carrier;
4) It can serve as a carrier for drug molecules, used for targeted drug delivery and controlled release;
5) It can be used for water treatment and pollutant adsorption, such as removing heavy metal ions and organic pollutants from water;
Characterizations
References
1) Zhou, Tian-You; Xu, Shun-Qi; Wen, Qiang; Pang, Zhong-Fu; Zhao, Xin; Journal of the American Chemical Society 2014 , 136(45), 15885-15888 ; DOI: 10.1021/ja5092936 ;One-Step Construction of Two Different Kinds of Pores in a 2D Covalent Organic Framework;