CAS:1630990-30-5
M.F.:C156H22O32Zr6
M.W.:2955.16868
Pricing
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Product: NU-1100
Synonyms: NA
CAS: 1630990-30-5
Basic Information
| Unit MF. | C156H22O32Zr6 | Unit MW. | 2955.16868 | ||
| Coordination Metal | Zr | Linkers |
4,4',4'',4'''-(pyrene-1,3,6,8-tetrayltetrakis(ethyne-2,1-diyl))tetrabenzoic acid |
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| Pore Size | 1–2 nm | Pore Volume | 0.44 cm3/g | ||
| Surface Area | 777 m²/g | ||||
| Analog Structure | NA | ||||
Product Property
| Appearance | Orange-red cubic crystals | |||
| Particle Size | NA | |||
Stability
1) Stable under green light irradiation and reaction conditions
2) Thermal decomposition temperature above 300°C
2) Thermal decomposition temperature above 300°C
Preservation
1) Store in dry and cool conditions
2) Activate by heating in a vacuum oven at room temperature for 3 hours before use
Other Features
1) Broad absorption in the visible light region, with an absorption edge red-shifted to below 600 nm
2) Bandgap of 2.12 eV
3) n-type semiconductor characteristics
2) Bandgap of 2.12 eV
3) n-type semiconductor characteristics
Applications
1) Efficient in photocatalytic oxidation of sulfides to sulfoxides under visible light
2) Useful as an electron transfer mediator in photocatalytic oxidation reactions
2) Useful as an electron transfer mediator in photocatalytic oxidation reactions
Characterizations
References
1) Bing Zeng, Fengwei Huang, Yuexin Wang, Kanghui Xiong, Xianjun Lang; Chinese Journal of Catalysis 2024, 58, 226–236, DOI: 10.1016/S1872-2067(23)64601-7; TEMPO radically expedites the conversion of sulfides to sulfoxides by pyrene-based metal-organic framework photocatalysis