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CuP-DHPh COF
CuP-DHPh COF
CAS:1606149-66-9
M.F.:(C44H32CuN8.C8H6O4)X
M.W.:902.46
Pricing
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Product: CuP-DHPh COF
Synonyms:Cu-DhaTph COF
CAS：1606149-66-9
Basic Information
| Unit MF. | C44H32CuN8.C8H6O4 | Unit MW. | 902.46 | ||
| Linkers |
1) TAPP-Cu(2+)（CAS: 67595-97-5） 2) 2,5-Diformylbenzene-1,4-diol (CAS: 1951-36-6) |
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| Aperture | 2.5 nm | Pore volume | cm3/g | ||
| Surface Area | BET比表面约为300+ m²/g | ||||
| Analog Structure |  |
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Product Property
| Appearance | powder |  |
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| Particle Size | The average particle size is about 75.1 nm | |||
Stability
1) The thermal decomposition temperature is about 400 ° C, and under acidic conditions, it may cause protonation of free radical porphyrins and demetallization of metalloporphyrins.
Preservation
1) Dry and sealed under normal temperature or low temperature conditions ；
2) Suggest using a 100 degree (vacuum) oven for activation for 12 hours before use；
Other Features
Fluorescence:NA
Applications
1) It can be used for the adsorption of gases and pollutants;
2) Due to its enhanced π - conjugation, it can be used for photocatalytic activity, especially in the production of singlet oxygen, showing excellent performance;
3) It may have applications in the field of organic semiconductors due to its improved crystallinity and enhanced porosity；
4) It can react with endogenous H2S to generate photothermal conversion agent CuS and synchronously release photosensitizer DhaTph, achieving local photothermal and photodynamic therapy at the tumor site;
Characterizations
References
1) Chen, Xiong; Addicoat, Matthew; Jin, Enquan; Zhai, Lipeng; Xu, Hong; Huang, Ning; Guo, Zhaoqi; Liu, Lili; Irle, Stephan; Jiang, Donglin ;Journal of the American Chemical Society 2015 , 137(9), 3241-3247 ; DOI: 10.1021/ja509602c ;Locking Covalent Organic Frameworks with Hydrogen Bonds: General and Remarkable Effects on Crystalline Structure, Physical Properties, and Photochemical Activity；
2) Feng, Jie; Ren, Wen-Xiu; Kong, Fei; Dong, Yu-Bin; Chemical Communications (Cambridge, United Kingdom) 2021, 57(59), 7240-7243 ; DOI: 10.1039/d1cc02258j ;A covalent organic framework-based nanoagent for H2S-activable phototherapy against colon cancer.