Product: MOF-74(Mg)
Synonyms: Mg-MOF-74; Mg-DOBDC; CPO-27(Mg); Mg2(dhtp)
CAS:1174268-74-6
Basic Information
Unit MF. |
C8H4O8Mg2 |
Unit MW. |
276.72256 |
Coordination Metal |
Mg |
Linkers |
2,5-Dihydroxyterephthalic acid (CAS: 610-92-4) |
Aperture |
1.2 nm
|
Pore volume |
0.65 cm3/g |
Surface Area |
BET Specific surface 1100 m2/g, |
Analog Structure |
 |
Product Property
Appearance |
Yellow Powders |
 |
Particle Size |
3-5um bulk particles |
Stability
1) MOF-74(Mg) is stable in air for weeks, but decomposed gradually in wet and hot conditions.
2) Thermal stability, thermal decomposition temperature above 450 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for >6 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (e.g. carbon dioxide & CH4) and pollutant air adsorption
2) MOF-74 is instable in acqueous solutions, thus it could be used for drug adsorption and release
Characterizations
References
1) J.K. Nathaniel, L. Rosi, Eddaoudi Mohamed, Banglin Chen, Michael O'Keeffe, Omar M. Yaghi, J. Am. Chem. Soc. 2005, 127, 1504–1518, DOI: 10.1021/ja045123o ; Rod packings and Metal−Organic frameworks constructed from rod-shaped secondary building units
2) Dietzel, Pascal D. C.; Blom, Richard; Fjellvaag, Helmer; European Journal of Inorganic Chemistry 2008, 23, 3624-3632, DOI: 10.1002/ejic.200701284 ; Base-Induced Formation of Two Magnesium Metal-Organic Framework Compounds with a Bifunctional Tetratopic Ligand