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TpPa-NO2
TpPa-NO2
CAS:1491156-84-3 M.F.:C9H6O6.C6H7N3O2 M.W.:363.27902
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Product: TpPa-NO2
Synonyms: NA
CAS:NA

Basic Information
Unit MF. NA Unit MW. NA
Linkers      
Pore Size 1.5 nm  Pore volume NA
Surface Area >300 m²/g 
Analog Structure NA
Product Property
Appearance dark reddish solid  
Particle Size irregular cluster particles
Stability
1) In aqueous solutions, stable in boiling water (100°C) for 7 days; stable in strong acids such as 12M HCl and 2M H₂SO₄ for 1 week, and  stable in 0.1M NaOH alkaline aqueous solution for 24 hours; .
2) Thermal stability:  stable at 300°C and starts to decompose after 350°C .
Preservation
1) Store at room temperature and keep dry. 
Other Features
Fluorescence: NA; 
Applications
1) Gas adsorption and separation: Selectively separate C₂H₄ from a C₂H₂/C₂H₄/CO₂ mixture and capture CO₂ from CO₂/N₂.
2) Removal of heavy metal ions: Used to adsorb various heavy metal ions after reduction and modification .
 
Characterizations
XRD
NA
SEM
NA
BET
NA
FTIR
NA
References
1) Suman Chandra, Sharath Kandambeth, Bishnu P. Biswal, Binit Lukose, Shrikant M. Kunjir, Minakshi Chaudhary, Ravichandar Babarao, Thomas Heine, Rahul Banerjee; Journal of the American Chemical Society 2013, 135(47), 17853 - 17861, DOI: 10.1021/ja408121p ; Chemically Stable Multilayered Covalent Organic Nanosheets from Covalent Organic Frameworks via Mechanical Delamination
2) Yunzhe Jiang, Chuanyao Liu, Aisheng Huang; ACS Applied Materials & Interfaces 2019, DOI: 10.1021/acsami.9b11850 ; EDTA - Functionalized Covalent Organic Framework for Removal of Heavy Metal Ions
3) Xiao - Hong Xiong, Liang Zhang, Wei Wang, Neng - Xiu Zhu, Lu - Zhu Qin, Huan - Feng Huang, Liu - Li Meng, Yang - Yang Xiong, Mihail Barboiu, Dieter Fenske, Peng Hu, Zhang - Wen Wei; ACS Applied Materials & Interfaces 2022, 14(30), 32105 - 32111, DOI: 10.1021/acsami.2c08338 ; Nitro - Decorated Microporous Covalent Organic Framework (TpPa - NO2) for Selective Separation of C2H4 from a C2H2/C2H4/CO2 Mixture and CO2 Capture
4) Weiliang Jin, Shaocong Li, Hongzhi Zhou, Shenghua Ma, Lina Zhu, Deming Kong; Advanced Functional Materials 2024, 34(2406834), DOI: 10.1002/adfm.202406834 ; Pore Wall Engineered Polar COFs as Size - Matched Nanotraps Enable Highly Efficient Capture of Long - Chain Alkylamines
TpPa-NO2
TpPa-NO2

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