CAS:1477485-46-3
M.F.:C23H16N2O8
M.W.:448.381746292114
Pricing
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Product: TpAQ-COF
Synonyms: TpAQ,DAAQ-TFP COF,1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy-, polymer with 2,6-diamino-9,10-anthracenedione
CAS：1477485-46-3
Basic Information
| Unit MF. | C23H16N2O8 | Unit MW. | 448.381746292114 | ||
| Coordination Metal | NA | Linkers |
1,3,5-triformylphloroglucinol (Tp) and 2,6-diaminoanthraquinone (AQ) |
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| Pore Size | ~1.2nm | Pore volume | NA | ||
| Surface Area | 1023 m²/g | ||||
| Analog Structure | NA | ||||
Product Property
| Appearance | Red powders, noodle-like nanofibers with an average diameter of about 200 nm | |||
| Particle Size | NA | |||
Stability
1) Stable in solution, recyclable with no significant performance decline after multiple cycles
2) Thermal decomposition temperature is above 400℃
2) Thermal decomposition temperature is above 400℃
Preservation
1) Keep in dry and Cool Condition
2) Activate by heating in a vacuum oven at room temperature for 3 hours before use
Other Features
1) Broad visible light absorption range covering almost the entire visible light region
2) Band gap of 2.02 eV
3) Superoxide radical anion (O₂⁻) is the key reactive oxygen species in photocatalytic selective oxidation reactions
2) Band gap of 2.02 eV
3) Superoxide radical anion (O₂⁻) is the key reactive oxygen species in photocatalytic selective oxidation reactions
Applications
1) Photocatalytic selective oxidation of amines to imines with green light and oxygen, showing good universality for various amines
2) Can be used as electrode materials and photothermal conversion materials
2) Can be used as electrode materials and photothermal conversion materials
Characterizations
References
1) Kanghui Xiong, Fulin Zhang, Yuexin Wang, Bing Zeng, Xianjun Lang; Journal of Colloid and Interface Science 2023, 643, 340–349, DOI: 10.1016/j.jcis.2023.04.017, Selective oxidation of amines powered with green light and oxygen over an anthraquinone covalent organic framework