Product: UIO-66-(COOH)2
Synonyms: NA
CAS:1458048-15-1
Basic Information
Unit MF. |
C60H2O56Zr6-12.H+ |
Unit MW. |
2166.97622 |
Coordination Metal |
Zr |
Linkers |
Pyromellitic acid (CAS: 89-05-4) |
Pore Size |
0.8nm; 1.1nm |
Pore volume |
0.5 cm3/g |
Surface Area |
BET Specific surface 200 m2/g, |
Analog Structure |
|
Product Property
Appearance |
Off-White Powder |
 |
Particle Size |
200-800nm |
Stability
1) UIO-66-(COOH)2 is stable in air, stable in aqueous and acidic conditions(stable in PH 1-12)
2)High thermal stability, thermal decomposition temperature above 350 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3-5 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) UIO-66-(COOH)2 has branch carboxylic groups, which could be used to bind with peptide or enzyme. The carboxylic groups might also be coordinated with metal ions, used as metal probes.
Characterizations
References
1) J. H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti, S. Bordiga, K. P. Lillerud, J. Am. Chem. Soc. 2008, 130, 13850-13851, DOI: 10.1021/ja8057953 ; A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
2) Z. Hu, Y. Peng, Z. Kang, Y. Qian, D. Zhao, Inorg. Chem. 2015, 54, 4862-4868, DOI: 10.1021/acs.inorgchem.5b00435 ; A Modulated Hydrothermal (MHT) Approach for the Facile Synthesis of UiO-66-Type MOFs