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1,3,5,7-Tetrakis(4-ethynylphenyl)adamantane
1,3,5,7-Tetrakis(4-ethynylphenyl)adamantane
CAS:144970-32-1 M.F.:C42H32 M.W.:536.70348
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Product Name:1,3,5,7-Tetrakis(4-ethynylphenyl)adamantane
Synonymous:TEPA
CAS:144970-32-1
Basic Info
M.F.  C42H32 M.W.  536.70348
Appearance  
Properties
1)  144970-32-1 is soluble in DCM、DMF, DMSO, etc.
2)  Sealed and stored at 2-8 ℃
Appications
1) It could be used as monomer linker for COF synthesis:PPN-2 [r2];  MPOF-Ad-1/2/3 [r3]; catPOPs [r4]; SNU-C1 [r5]
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Mathias, L.; Reichert, V.; Muir, Andrew V. G.; Chem. Mater. 1993, 5(1), 4-5, DOI:10.1021/cm00025a002 ; Synthesis of rigid tetrahedral tetrafunctional molecules from 1,3,5,7-tetrakis(4-iodophenyl)adamantane 
2) Lu, W.; Yuan, D.; Zhao, D.; Schilling, C. I.; Plietzsch, O.; Muller, T.; Brase, S.; Guenther, J.; Blumel, J.; Krishna, R.; Li, Z.; Zhou, H.-C. Chem. Mater. 2010, 22, 5964– 5972, DOI: 10.1021/cm1021068 ; Porous Polymer Networks: Synthesis, Porosity, and Applications in Gas Storage/Separation 
3) Wen, W.; Shuttleworth, P.; Yue, H.; Fernandez-Blazquez, J.; Guo, J.; ACS Appl. Mater. Interfaces 2020, 12, 6, 7548-7556, DOI: 10.1021/acsami.9b20771 ; Exceptionally Stable Microporous Organic Frameworks with Rigid Building Units for Efficient Small Gas Adsorption and Separation 
4) Totten, R.; Weston, M.; Park, J.; Farha, O.; Hupp, J.; Nguyen, S.; ACS Catal. 2013, 3, 7, 1454-1459, DOI: 10.1021/cs4001738
5) Xie, L.; Suh, M.; Chem.- Euro. J. 2013, 19(35), 11590-11597, DOI: 10.1002/chem.201301822
1,3,5,7-Tetrakis(4-ethynylphenyl)adamantane
1,3,5,7-Tetrakis(4-ethynylphenyl)adamantane

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